The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 09, 2019

Filed:

Jun. 17, 2016
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Jihad M. Dakka, Whitehouse Station, NJ (US);

Ashley J. Malik, Houston, TX (US);

Christopher L. Becker, Manhattan, KS (US);

Jason D. Davis, Zachary, LA (US);

Kirk C. Nadler, Houston, TX (US);

Jose M. Vargas, Friendswood, TX (US);

Tan-Jen Chen, Seattle, WA (US);

Seth M. Washburn, Houston, TX (US);

Jörg F. W. Weber, Houston, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/82 (2006.01); C07C 45/00 (2006.01); C07C 37/74 (2006.01);
U.S. Cl.
CPC ...
C07C 45/006 (2013.01); C07C 37/74 (2013.01); C07C 45/82 (2013.01); C07C 2601/14 (2017.05); Y02P 20/52 (2015.11);
Abstract

Disclosed are novel processes for making cyclohexanone compositions, from a mixture comprising phenol, cyclohexanone, and cyclohexylbenzene. The process includes hydrogenation of a feed stream comprising phenol, cyclohexanone, and cyclohexylbenzene. The feed stream may be subjected to one or more pre-hydrogenation treatments, such as passing through one or more sorbents, addition of basic chemical agents, and/or addition of water, so as to improve catalyst activity, minimize undesired side reactions, and/or remove catalyst poisons from the feed stream. The feed stream may be provided to a hydrogenation reaction zone in the vapor phase, with periodic alterations to hydrogenation reaction conditions such that the feed is provided in mixed liquid and vapor phase in order to carry out liquid washing of a hydrogenation catalyst bed within the hydrogenation reaction zone.


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