The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 19, 2019

Filed:

Jul. 11, 2016
Applicant:

Tianjin University, Tianjin, CN;

Inventors:

Jijun Zou, Tianjin, CN;

Lun Pan, Tianjin, CN;

Xiangwen Zhang, Tianjin, CN;

Qingfa Wang, Tianjin, CN;

Li Wang, Tianjin, CN;

Assignee:

TIANJIN UNIVERSITY, Tianjin, CN;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 1/20 (2006.01); C07C 2/86 (2006.01); C07C 29/32 (2006.01); C07C 45/61 (2006.01); C07C 13/567 (2006.01);
U.S. Cl.
CPC ...
C07C 1/20 (2013.01); C07C 2/864 (2013.01); C07C 2/865 (2013.01); C07C 13/567 (2013.01); C07C 29/32 (2013.01); C07C 45/61 (2013.01); C07C 2603/10 (2017.05);
Abstract

The present invention discloses a process for preparing perhydrofluorene or alkyl-substituted perhydrofluorene, comprising the steps of: (1) reacting a phenolic compound or an aromatic hydrocarbon compound or an aromatic ketone compound or an aromatic ether compound with a benzyl compound to carry out an alkylation reaction in the presence of a first catalyst, thereby to produce substituted or unsubstituted diphenyl methane, wherein the first catalyst is an acidic catalyst; and (2) reacting the substituted or unsubstituted diphenyl methane with hydrogen gas to carry out an hydrogenation reaction or a hydrodeoxygenation reaction, thereby to produce perhydrofluorene or alkyl-substituted perhydrofluorene, wherein the second catalyst is a physical mixture of a metal catalyst and an acidic catalyst or a metal catalyst loaded on an acidic catalyst.


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