The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 12, 2019

Filed:

Apr. 22, 2013
Applicants:

Solvay SA, Brussels, BE;

Centre National DE LA Recherche Scientifique, Paris, FR;

Inventors:

Julio A. Abusleme, Saronno, IT;

Jean Le Bideau, Nantes, FR;

Aurélie Guyomard-Lack, Beaucouzé, FR;

Dominique Guyomard, Sautron, FR;

Bernard Lestriez, Nantes, FR;

Assignees:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 10/0565 (2010.01); H01M 10/0567 (2010.01); H01M 10/0569 (2010.01); H01M 8/10 (2016.01); C09K 9/00 (2006.01); G02F 1/00 (2006.01); H01G 9/20 (2006.01); C08J 5/18 (2006.01); H01M 8/1023 (2016.01); H01M 8/1037 (2016.01); H01M 8/1039 (2016.01); H01M 8/1044 (2016.01); H01M 8/1048 (2016.01); H01M 8/1051 (2016.01); C09K 9/02 (2006.01); G02F 1/15 (2006.01); H01M 8/1018 (2016.01);
U.S. Cl.
CPC ...
C08J 5/18 (2013.01); C09K 9/02 (2013.01); H01G 9/2009 (2013.01); H01M 8/1023 (2013.01); H01M 8/1037 (2013.01); H01M 8/1039 (2013.01); H01M 8/1044 (2013.01); H01M 8/1048 (2013.01); H01M 8/1051 (2013.01); H01M 10/0565 (2013.01); H01M 10/0567 (2013.01); H01M 10/0569 (2013.01); C08J 2327/16 (2013.01); G02F 2001/1519 (2013.01); H01M 2008/1095 (2013.01); H01M 2300/0045 (2013.01); H01M 2300/0082 (2013.01); Y02E 10/542 (2013.01); Y02P 70/521 (2015.11); Y02P 70/56 (2015.11);
Abstract

The invention pertains to a process for manufacturing a fluoropolynner film comprising a fluoropolymer hybrid organic/inorganic composite, said process comprising the following steps: (i) providing a mixture of: —at least one fluoropolymer [polymer (F)]; —at least one metal compound [compound (M)] having formula: XAYwherein m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group and X is a hydrocarbon group, optionally comprising one or more functional groups; —a liquid medium consisting essentially of at least one ionic liquid (IL) and, optionally, at least one additive (A); —optionally, at least one electrolytic salt (ES); and —optionally, at least one organic solvent (S); (ii) hydrolyzing and/or polycondensing said compound (M) to yield a liquid mixture comprising fluoropolymer hybrid organic/inorganic composite comprising inorganic domains and incorporating said liquid medium; (iii) processing a film from the liquid mixture obtained in step (ii); and (iv) drying and then, optionally, curing the film obtained in step (iii) for obtaining the fluoropolymer film. The invention also pertains to the fluoropolymer film obtained from said process and to use of said fluoropolymer film in electrochemical and photo-electrochemical devices.


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