The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 26, 2019

Filed:

Jul. 22, 2015
Applicant:

Uchicago Argonne, Llc, Chicago, IL (US);

Inventors:

Christopher Johnson, Naperville, IL (US);

Sun-Ho Kang, Naperville, IL (US);

Assignee:

UCHICAGO ARGONNE, LLC, Chicago, IL (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C01D 15/02 (2006.01); H01M 4/04 (2006.01); C01G 53/00 (2006.01); H01B 1/12 (2006.01); H01M 4/505 (2010.01); H01M 4/525 (2010.01); H01M 10/0525 (2010.01); H01M 4/02 (2006.01); H01M 4/131 (2010.01); H01M 10/052 (2010.01);
U.S. Cl.
CPC ...
C01D 15/02 (2013.01); C01G 53/44 (2013.01); H01B 1/122 (2013.01); H01M 4/0471 (2013.01); H01M 4/505 (2013.01); H01M 4/525 (2013.01); C01P 2002/32 (2013.01); C01P 2002/50 (2013.01); C01P 2002/52 (2013.01); C01P 2002/72 (2013.01); C01P 2004/03 (2013.01); C01P 2004/61 (2013.01); C01P 2006/40 (2013.01); H01M 4/131 (2013.01); H01M 10/052 (2013.01); H01M 10/0525 (2013.01); H01M 2004/021 (2013.01); Y02E 60/122 (2013.01);
Abstract

A positive electrode is disclosed for a non-aqueous electrolyte lithium rechargeable cell or battery. The electrode comprises a lithium containing material of the formula NaLiNiMnMO, wherein M is a metal cation, x+y>1, 0<z<0.5, 0≤z'<0.5, y+x+1 is less than d, and the value of d depends on the proportions and average oxidation states of the metallic elements, Li, Na, Mn, Ni, and M, if present, such that the combined positive charge of the metallic elements is balanced by the number of oxygen anions, d. The inventive material preferably has a spinel or spinel-like component in its structure. The value of y preferably is less than about 0.2, and M comprises one or more metal cations selected preferably from one or more monovalent, divalent, trivalent or tetravalent cations, such as Mg, Co, Co, B, Ga, Fe, Fe, Al, and Ti. The electrode material can be synthesized using an ion-exchange reaction with a lithium salt in an organic-based solvent to partially replace sodium ions of a precursor material with lithium ions.


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