The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 19, 2019

Filed:

Feb. 17, 2016
Applicant:

California Institute of Technology, Pasadena, CA (US);

Inventors:

Nicholas J. Weadock, Pasadena, CA (US);

Hongjin Tan, Pasadena, CA (US);

Brent T. Fultz, Pasadena, CA (US);

Heng Yang, Pasadena, CA (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C23C 8/08 (2006.01); H01M 4/38 (2006.01); C22C 14/00 (2006.01); C22C 27/02 (2006.01); C22C 1/02 (2006.01); C22F 1/18 (2006.01); C21D 1/60 (2006.01); C21D 1/58 (2006.01); C21D 1/613 (2006.01); B22D 18/06 (2006.01); B22D 11/06 (2006.01); C23C 8/80 (2006.01); H01M 4/62 (2006.01); C22C 1/04 (2006.01); B22F 9/04 (2006.01); H01M 10/34 (2006.01); H01M 12/08 (2006.01);
U.S. Cl.
CPC ...
H01M 4/383 (2013.01); B22D 11/06 (2013.01); B22D 18/06 (2013.01); C21D 1/58 (2013.01); C21D 1/60 (2013.01); C21D 1/613 (2013.01); C22C 1/02 (2013.01); C22C 1/045 (2013.01); C22C 14/00 (2013.01); C22C 27/025 (2013.01); C22F 1/18 (2013.01); C22F 1/183 (2013.01); C23C 8/08 (2013.01); C23C 8/80 (2013.01); H01M 4/621 (2013.01); B22F 2009/043 (2013.01); B22F 2998/10 (2013.01); H01M 10/345 (2013.01); H01M 12/08 (2013.01); Y02E 60/128 (2013.01);
Abstract

Methods of preparing improved metal hydride alloy materials are provided. The alloys include a mixture of at least four of vanadium, titanium, nickel, chromium, and iron. The alloy is processed by at least one of thermal and physical treatment to generate a refined microstructure exhibiting improved kinetics when used as electrodes in MH batteries (e.g., higher discharge current). The thermal treatment includes rapid cooling of the alloy at greater than 10K/s. The physical treatment includes mechanical pulverization of the alloy after cooling. The microstructure is a single phase (body centered cubic) with a heterogeneous composition including a plurality of primary regions having a lattice parameter selected from the range of 3.02 Å to 3.22 Å and a plurality of secondary regions having a lattice parameter selected from the range of 3.00 Å to 3.22 Å and at least one physical dimension having a maximum average value less than 1 μm.


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