The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 05, 2019

Filed:

Sep. 07, 2016
Applicant:

Basf SE, Ludwigshafen am Rhein, DE;

Inventors:

Kai-Uwe Schoening, Oberwil, CH;

Walid A. Al-Akhdar, Cary, NC (US);

Tiziano Nocentini, Birsfelden, CH;

Gerard Vilain, Breisach, DE;

Assignee:

BASF SE, Ludwigshafen am Rhein, DE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 37/14 (2006.01); B01J 31/00 (2006.01); B01J 31/22 (2006.01);
U.S. Cl.
CPC ...
C07C 37/14 (2013.01); B01J 31/00 (2013.01); B01J 31/2226 (2013.01);
Abstract

The present invention relates to a process for the preparation of 2,6-di-tert-butyl phenol by reacting phenol with isobutylene in presence of an aluminum phenoxide catalyst, comprising i) preparing an aluminum phenoxide catalyst and phenol comprising mixture a) by mix-ing aluminum metal with phenol, and activating the catalyst by heating the mixture to a temperature of 100 to 180° C., and ii) carrying out a reaction b) by reacting mixture a) with an isobutylene comprising stream comprising 20 to 90% by weight of isobutylene and 10 to 80% by weight of 1-butene and/or 2-butene, which reaction is carried out under pressure and the maximum pressure is 5 to 20 bar.


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