The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 05, 2019

Filed:

Jun. 15, 2017
Applicant:

Evonik Degussa Gmbh, Essen, DE;

Inventors:

Guido Stochniol, Haltern am See, DE;

Helene Reeker, Dortmund, DE;

Dietrich Maschmeyer, Recklinghausen, DE;

Stephan Peitz, Oer-Erkenschwick, DE;

Jörg Schallenberg, Dorsten, DE;

Assignee:

Evonik Degussa GmbH, Essen, DE;

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B01D 3/14 (2006.01); C07C 1/20 (2006.01); C07C 2/04 (2006.01); C07C 2/10 (2006.01); C07C 2/24 (2006.01); C07C 2/26 (2006.01); B01J 19/18 (2006.01); C01B 33/12 (2006.01); C01F 11/02 (2006.01); C07C 11/02 (2006.01); C07C 11/08 (2006.01); C07C 41/06 (2006.01); C07C 43/04 (2006.01); C07C 11/107 (2006.01); C07C 11/113 (2006.01);
U.S. Cl.
CPC ...
C07C 2/04 (2013.01); B01D 3/14 (2013.01); B01J 19/18 (2013.01); C01B 33/12 (2013.01); C01F 11/02 (2013.01); C07C 1/20 (2013.01); C07C 2/10 (2013.01); C07C 2/24 (2013.01); C07C 2/26 (2013.01); C07C 41/06 (2013.01); C07C 2521/06 (2013.01); C07C 2521/08 (2013.01); C07C 2521/10 (2013.01); C07C 2523/26 (2013.01); C07C 2523/745 (2013.01); C07C 2523/755 (2013.01); C07C 2531/12 (2013.01); Y02P 20/52 (2015.11); Y02P 30/42 (2015.11);
Abstract

The invention is concerned with the production of 1-hexene and octenes from ethene. 1-Butene is optionally also to be produced. The problem addressed by the present invention is that of developing a process for producing 1-hexene from ethene by MTHxE etherification to achieve better chemical utilization of the employed carbon atoms. This problem is solved by catalytic retrocleavage of MTHxE into the Colefins and the alcohol, reuse of the alcohol in the etherification and reaction of the obtained Colefins with ethene to afford Colefins. In this way the alcohol is not lost from the process but rather is internally recirculated as a derivatizing agent. The less attractive Colefins from the cleavage product are upgraded to octene with further ethene in order to provide a further commercial product.


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