The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 18, 2018

Filed:

Nov. 18, 2016
Applicants:

Massachusetts Institute of Technology, Cambridge, MA (US);

Luxembourg Institute of Science and Technology, Belvaux, LU;

Inventors:

Karen K. Gleason, Cambridge, MA (US);

Minghui Wang, Quincy, MA (US);

Nicolas D. Boscher, Audun-le-Tiche, FR;

Patrick Choquet, Longeville-les-Metz, FR;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 61/12 (2006.01); C23C 16/505 (2006.01); B05D 1/00 (2006.01); B01D 69/12 (2006.01); C01B 3/50 (2006.01); C08F 34/00 (2006.01); C08F 134/00 (2006.01); C08J 5/22 (2006.01); C08F 234/00 (2006.01); C09D 145/00 (2006.01); B01D 53/22 (2006.01); B01D 67/00 (2006.01); B01D 69/14 (2006.01); B01D 71/00 (2006.01); C01B 21/04 (2006.01); C01B 13/02 (2006.01);
U.S. Cl.
CPC ...
C08G 61/124 (2013.01); B01D 53/228 (2013.01); B01D 67/0037 (2013.01); B01D 67/0072 (2013.01); B01D 69/127 (2013.01); B01D 69/148 (2013.01); B01D 71/00 (2013.01); B05D 1/62 (2013.01); C01B 3/503 (2013.01); C01B 13/0255 (2013.01); C01B 21/04 (2013.01); C08F 34/00 (2013.01); C08F 134/00 (2013.01); C08F 234/00 (2013.01); C08J 5/2231 (2013.01); C09D 145/00 (2013.01); C23C 16/505 (2013.01); B01D 2323/30 (2013.01); C08G 2261/228 (2013.01); C08G 2261/312 (2013.01); C08G 2261/3241 (2013.01); C08G 2261/37 (2013.01); C08G 2261/61 (2013.01);
Abstract

Described herein are facile, one-step initiated plasma enhanced chemical vapor deposition (iPECVD) methods of synthesizing hyper-thin (e.g., sub-100 nm) and flexible metal organic covalent network (MOCN) layers. As an example, the MOCN may be made from zinc tetraphenylporphyrin (ZnTPP) building units. When deposited on a membrane support, the MOCN layers demonstrate gas separation exceeding the upper bounds for multiple gas pairs while reducing the flux as compared to the support alone.


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