The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 11, 2018

Filed:

Oct. 09, 2015
Applicant:

Nok Corporation, Tokyo, JP;

Inventors:

Masataka Kondo, Shizuoka, JP;

Kensuke Watanabe, Sizuoka, JP;

Hirokazu Yamamoto, Shizuoka, JP;

Assignee:

NOK Corporation, Tokyo, JP;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01D 53/22 (2006.01); B01D 69/08 (2006.01); C01B 31/02 (2006.01); B01D 71/02 (2006.01); B01D 69/14 (2006.01); C01B 32/05 (2017.01);
U.S. Cl.
CPC ...
B01D 69/087 (2013.01); B01D 53/228 (2013.01); B01D 69/08 (2013.01); B01D 69/141 (2013.01); B01D 71/021 (2013.01); C01B 31/02 (2013.01); C01B 32/05 (2017.08); B01D 2053/224 (2013.01);
Abstract

A membrane-forming dope for carbon membranes, comprising polyphenylene oxide in an amount giving a concentration of 15 to 40 wt. % in the membrane-forming dope, and sulfur in an amount giving a ratio of 0.1 to 5.0 wt. %, preferably 0.2 to 3.0 wt. %, of the total weight of the polyphenylene oxide and the sulfur, both of which are dissolved in a solvent that can dissolve these components. A hollow fiber carbon membrane is produced by molding the membrane-forming dope for carbon membranes in a hollow shape by means of a wet or dry-wet spinning method using a double tubular nozzle, subjecting the molded product to an infusibilization treatment by heating at 150 to 350° C. in the air, and then subjecting it to a carbonization treatment by heating at 600 to 800° C. in an inert atmosphere or under vacuum. When the product molded in a hollow shape by means of a wet or dry-wet spinning method is subjected to an infusibilization treatment by heating in the air while stretching the product with a stress of 0.002 to 0.005 MPa, a hollow fiber carbon membrane having excellent gas permeability and a further high gas separation factor (He/CH) can be obtained.


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