The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 04, 2018

Filed:

Jul. 17, 2015
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Jane C. Cheng, Bethlehem, PA (US);

Xiaobo Zheng, Houston, TX (US);

Hari Nair, Somerville, NJ (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 5/27 (2006.01); B01J 29/04 (2006.01); B01J 35/02 (2006.01); B01J 19/00 (2006.01); B01J 8/04 (2006.01); B01J 23/36 (2006.01); B01J 29/40 (2006.01); B01J 29/80 (2006.01); B01J 37/00 (2006.01); B01J 37/02 (2006.01);
U.S. Cl.
CPC ...
B01J 35/023 (2013.01); B01J 8/0453 (2013.01); B01J 8/0457 (2013.01); B01J 19/0093 (2013.01); B01J 23/36 (2013.01); B01J 29/40 (2013.01); B01J 29/80 (2013.01); B01J 37/0018 (2013.01); B01J 37/0201 (2013.01); C07C 5/2708 (2013.01); C07C 5/2724 (2013.01); C07C 5/2737 (2013.01); C07C 5/2754 (2013.01); B01J 2208/00716 (2013.01); B01J 2208/025 (2013.01); B01J 2208/027 (2013.01); B01J 2219/00792 (2013.01); B01J 2219/00835 (2013.01); B01J 2219/00873 (2013.01); B01J 2219/00961 (2013.01); B01J 2229/32 (2013.01); C07C 2529/48 (2013.01); Y02P 20/52 (2015.11);
Abstract

A catalyst system is disclosed for producing para-xylene from a Chydrocarbon mixture comprising ethylbenzene and at least one xylene isomer other than para-xylene. The catalyst system comprises a first catalyst bed and a second catalyst bed. The first catalyst bed comprises a first zeolite and a rhenium hydrogenation component. The first zeolite has a constraint index from 1 to 12, an average crystal size from 0.1 to 1 micron and has been selectivated to have an ortho-xylene sorption time of greater than 1200 minutes based on its capacity to sorb 30% of the equilibrium capacity of ortho-xylene at 120° C. and an ortho-xylene partial pressure of 4.5±0.8 mm of mercury. The second catalyst bed comprises a second zeolite and a rhenium hydrogenation component. The second zeolite has a constraint index ranging from 1 to 12 and an average crystal size of less than 0.1 micron.


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