The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 27, 2018

Filed:

Oct. 28, 2015
Applicants:

The Regents of the University of California, Oakland, CA (US);

Bp Corporation North America Inc., Houston, TX (US);

Inventors:

Shylesh Sankaranarayanapillai, Albany, CA (US);

Sanil Sreekumar, Midland, MI (US);

F. Dean Toste, Piedmont, CA (US);

Alexis T. Bell, Oakland, CA (US);

Amit A. Gokhale, Scotch Plains, NJ (US);

Adam Grippo, Oakland, CA (US);

George E. Arab, Berkeley, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/74 (2006.01); B01J 31/02 (2006.01); C10L 1/02 (2006.01); C10G 3/00 (2006.01); B01J 31/04 (2006.01); C07C 1/207 (2006.01); C07C 49/203 (2006.01); C10M 105/04 (2006.01); C12P 7/26 (2006.01);
U.S. Cl.
CPC ...
C07C 45/74 (2013.01); B01J 31/0201 (2013.01); B01J 31/0204 (2013.01); B01J 31/0222 (2013.01); B01J 31/0225 (2013.01); B01J 31/0237 (2013.01); B01J 31/0238 (2013.01); B01J 31/0244 (2013.01); B01J 31/0251 (2013.01); B01J 31/0254 (2013.01); B01J 31/0259 (2013.01); B01J 31/0271 (2013.01); B01J 31/04 (2013.01); C07C 1/2076 (2013.01); C07C 49/203 (2013.01); C10G 3/50 (2013.01); C10L 1/02 (2013.01); C10M 105/04 (2013.01); C12P 7/26 (2013.01); B01J 2231/342 (2013.01); C10M 2203/022 (2013.01); Y02P 30/20 (2015.11);
Abstract

Provided herein are methods for producing α,β-unsaturated ketones from the condensation of methyl ketones in the presence of an amine catalyst. Such amine catalysts may be supported, for example, on a silica-alumina support. Such amine catalysts may be used in the presence of an additional acid. The α,β-unsaturated ketones may be produced by dimerization and/or timerization of the methyl ketones. Such α,β-unsaturated ketones may be suitable for use in producing fuels, gasoline additives, and/or lubricants, or precursors thereof. The methyl ketones may be obtained from renewable sources, such as by the fermentation of biomass.


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