The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 20, 2018

Filed:

Dec. 01, 2014
Applicant:

3m Innovative Properties Company, St. Paul, MN (US);

Inventors:

Tzu-Chen Lee, Woodbury, MN (US);

Robert J. DeVoe, Minnetonka, MN (US);

Brian K. Nelson, Shoreview, MN (US);

Brian J. Gates, Osceola, WI (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
G03F 7/00 (2006.01); G03F 7/039 (2006.01); G03F 7/16 (2006.01); G03F 7/20 (2006.01); G03F 7/30 (2006.01); C08F 2/50 (2006.01); G03F 7/027 (2006.01); G03F 7/031 (2006.01); G03F 7/038 (2006.01); C08F 222/10 (2006.01);
U.S. Cl.
CPC ...
G03F 7/0037 (2013.01); C08F 2/50 (2013.01); G03F 7/027 (2013.01); G03F 7/031 (2013.01); G03F 7/038 (2013.01); G03F 7/039 (2013.01); G03F 7/16 (2013.01); G03F 7/20 (2013.01); G03F 7/2012 (2013.01); G03F 7/2053 (2013.01); G03F 7/30 (2013.01); C08F 2222/1026 (2013.01);
Abstract

A method of fabricating a structure includes disposing a liquid photoreactive composition on a substrate, exposing a portion of the liquid photoreactive composition to laser light of sufficient intensity and wavelength to cause polymerization via two-photon excitation of the two-photon sensitizer and polymerization of a portion of the liquid photoreactive composition thereby providing an exposed composition; and developing the exposed composition to provide the structure. The liquid composition includes: at least one cationically polymerizable polyepoxide; at least one compound comprising free-radically polymerizable groups; an effective amount of a two-photon photoinitiator system, wherein the weight ratio of component (a) to component (b) is from 25:75 to 75:25, inclusive. The two-photon photoinitiator system includes a two-photon sensitizer and an aromatic onium salt. The liquid photoreactive composition may contain less than about one percent by weight of organic solvent.


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