The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 06, 2018

Filed:

Jun. 01, 2015
Applicant:

Sabic Global Technologies B.v., Bergen op Zoom, NL;

Inventors:

Andrew Davies, Cleveland, GB;

Dustin Fickel, Houston, TX (US);

Maikel Van Iersel, Den Bosch, NL;

Assignee:

SABIC GLOBAL TECHNOLOGIES B.V., Bergen op Zoom, NL;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 4/06 (2006.01); C10G 47/02 (2006.01); B01J 29/40 (2006.01); B01J 29/44 (2006.01); C10G 45/62 (2006.01); C10G 45/64 (2006.01); C10G 45/70 (2006.01); C10G 47/00 (2006.01); C10G 47/14 (2006.01); C10G 47/18 (2006.01); C10G 63/00 (2006.01); C10G 63/08 (2006.01); B01J 37/04 (2006.01); B01J 35/00 (2006.01); B01J 21/04 (2006.01); B01J 23/42 (2006.01);
U.S. Cl.
CPC ...
C07C 4/06 (2013.01); B01J 21/04 (2013.01); B01J 23/42 (2013.01); B01J 29/40 (2013.01); B01J 29/44 (2013.01); B01J 35/0006 (2013.01); B01J 37/04 (2013.01); C10G 45/62 (2013.01); C10G 45/64 (2013.01); C10G 45/70 (2013.01); C10G 47/00 (2013.01); C10G 47/14 (2013.01); C10G 47/18 (2013.01); C10G 63/00 (2013.01); C10G 63/08 (2013.01); C07C 2529/44 (2013.01); C10G 2300/1044 (2013.01); C10G 2300/301 (2013.01); C10G 2300/4056 (2013.01); C10G 2300/4081 (2013.01); C10G 2300/708 (2013.01); C10G 2400/30 (2013.01); Y02P 20/52 (2015.11);
Abstract

The invention relates to a process for producing benzene, comprising the steps of: (a) providing a hydrocracking feed stream comprising C5-C12 hydrocarbons, (b) contacting the hydrocracking feed stream in the presence of hydrogen with a hydrocracking catalyst comprising 0.01-1 wt-% hydrogenation metal in relation to the total catalyst weight and a zeolite having a pore size of 5-8 A and a silica (SiO2) to alumina (AlO) molar ratio of 5-200 under process conditions including a temperature of 425-580° C., a pressure of 300-5000 kPa gauge and a Weight Hourly Space Velocity of 0.1-15 hto produce a hydrocracking product stream comprising benzene, toluene and C8+ hydrocarbons, (c) separating benzene, toluene and the C8+ hydrocarbons from the hydrocracking product stream and (d) selectively recycling back at least part of the toluene from the separated products of step (c) to be included in the hydrocracking feed stream process for producing benzene from a c5-c12 hydrocarbon mixture


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