The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 23, 2018

Filed:

Feb. 04, 2014
Applicant:

Saudi Basic Industries Corporation, Riyadh, SA;

Inventors:

Jaap W. van Hal, Fresno, TX (US);

Scott A. Stevenson, Houston, TX (US);

Jim Allman, Sugar Land, TX (US);

David L. Sullivan, Sugar Land, TX (US);

Travis Conant, Sugar Land, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/76 (2006.01); C07C 6/04 (2006.01); C07C 5/41 (2006.01);
U.S. Cl.
CPC ...
C07C 2/76 (2013.01); C07C 5/417 (2013.01); C07C 6/04 (2013.01); C07C 2521/04 (2013.01); C07C 2521/08 (2013.01); C07C 2523/28 (2013.01); C07C 2523/30 (2013.01); C07C 2523/36 (2013.01); C07C 2529/54 (2013.01); C07C 2529/62 (2013.01);
Abstract

The disclosure is for a process for producing propylene and hexene (along with ethylene, pentenes, product butenes, heptenes and octenes) by metathesis from butenes (iso-, 1- and cis and trans 2-) and pentenes and then aromatizing the hexenes (along with higher olefins, such as heptenes and octenes) to benzene (along with toluene, xylenes, ethylbenzene and styrene). Since the desired products of the metathesis reaction are propylene and hexene, the feed to the metathesis reaction has a molar ratio for 1-butene:2-butene which favors production of propylene and 3-hexene with the concentration of hexenes and higher olefins in the metathesis product being up to 30 mole %. An isomerization reactor may be used to obtain the desired molar ratio of 1-butene:2-butene for the feed composition into the metathesis reactor. After the metathesis reaction, of hexene and higher olefins are separated for aromatization to benzene and other aromatics.


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