The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 02, 2018

Filed:

Oct. 28, 2014
Applicants:

China Petroleum & Chemical Corporation, Beijing, CN;

Fushun Research Institute of Petroleum and Petrochemicals, Sinopec Corp., Fushun, Liaoning, CN;

Inventors:

Xiangchen Fang, Liaoning, CN;

Shudong Zhang, Liaoning, CN;

Xinwei Zhang, Liaoning, CN;

Xiwen Zhang, Liaoning, CN;

Xiaodan Sun, Liaoning, CN;

Jie Li, Liaoning, CN;

Xiangqian Ni, Liaoning, CN;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07C 1/30 (2006.01); B01J 29/40 (2006.01); B01J 37/22 (2006.01); B01J 27/138 (2006.01); C07C 1/26 (2006.01); B01J 37/18 (2006.01); B01J 23/06 (2006.01); B01J 23/10 (2006.01); B01J 35/10 (2006.01); B01J 35/00 (2006.01); B01J 37/02 (2006.01);
U.S. Cl.
CPC ...
C07C 1/30 (2013.01); B01J 27/138 (2013.01); B01J 29/405 (2013.01); B01J 37/18 (2013.01); B01J 37/22 (2013.01); C07C 1/26 (2013.01); B01J 23/06 (2013.01); B01J 23/10 (2013.01); B01J 35/002 (2013.01); B01J 35/1019 (2013.01); B01J 35/1042 (2013.01); B01J 37/0201 (2013.01); C07C 2521/04 (2013.01); C07C 2527/138 (2013.01); C07C 2529/40 (2013.01);
Abstract

Provided are a supported catalyst, a preparation method therefor and use thereof, and a method for the preparation of isobutylene from halomethane. The catalyst is characterized in that it comprises a carrier and a metallic active component supported on the carrier, wherein the metallic active component comprises zinc oxide and zinc halide. On the basis of the total amount of the catalyst, by weight content, the content of zinc oxide is 0.5%-20%, the content of zinc halide is 10%-50%, and the content of the support is 40%-88%. Compared with the prior art, the catalyst of the present invention can convert halomethane into isobutylene with a high selectivity. With the reaction for preparing of isobutylene by converting bromomethane according to the method of the present invention, the conversion of bromomethane is not less than 90% and the selectivity of isobutylene is not less than 80%.


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