The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 25, 2018

Filed:

Aug. 27, 2015
Applicant:

Shin-etsu Chemical Co., Ltd., Tokyo, JP;

Inventors:

Miyoshi Yamashita, Joetsu, JP;

Takeshi Kinsho, Joetsu, JP;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C12P 7/62 (2006.01); C07C 69/78 (2006.01); C07C 67/08 (2006.01); C07C 303/28 (2006.01); C07C 29/80 (2006.01); C07C 67/10 (2006.01); C07C 67/54 (2006.01); C07C 29/09 (2006.01);
U.S. Cl.
CPC ...
C12P 7/62 (2013.01); C07C 29/095 (2013.01); C07C 29/80 (2013.01); C07C 67/08 (2013.01); C07C 67/10 (2013.01); C07C 67/54 (2013.01); C07C 69/78 (2013.01); C07C 303/28 (2013.01); C07B 2200/07 (2013.01); C07B 2200/09 (2013.01);
Abstract

Provided are methods including a method for industrially producing (2S,12Z)-2-acetoxy-12-heptadecene, which is, for example, a sex pheromone of pistachio twig borer. The methods can include a production method comprising a step of reacting racemic (2RS,12Z)-2-hydroxy-12-heptadecene with vinyl benzoate in the presence of a lipase to obtain a mixture of optically active (2R,12Z)-2-benzoyloxy-12-heptadecene of Formula (R,Z-2) and optically active (2S,12Z)-2-hydroxy-12-heptadecene of Formula (S,Z-1), a step of heating the mixture to distill out the optically active (2S,12Z)-2-hydroxy-12-heptadecene (S,Z-1), and a step of acetylating the optically active (2S,12Z)-2-hydroxy-12-heptadecene (S,Z-1) to obtain optically active (2S,12Z)-2-acetoxy-12-heptadecene of Formula (S,Z-3).


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