The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 18, 2018

Filed:

Oct. 17, 2016
Applicant:

Archer-daniels-midland Company, Decatur, IL (US);

Inventors:

Eric L. Dias, Belmont, CA (US);

Vincent J. Murphy, San Jose, CA (US);

James A. W. Shoemaker, Gilroy, CA (US);

Assignee:

Archer-Daniels-Midland Company, Decatur, IL (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 55/00 (2006.01); C07C 51/235 (2006.01); B01J 23/42 (2006.01); B01J 21/06 (2006.01); B01J 23/652 (2006.01); B01J 35/10 (2006.01);
U.S. Cl.
CPC ...
C07C 51/235 (2013.01); B01J 21/066 (2013.01); B01J 23/42 (2013.01); B01J 23/6527 (2013.01); B01J 35/1014 (2013.01); B01J 35/1019 (2013.01); B01J 35/1061 (2013.01); B01J 35/1066 (2013.01);
Abstract

Processes are disclosed for the conversion of 1,6-hexanediol to adipic acid employing a chemocatalytic reaction in which 1,6-hexanediol is reacted with oxygen in the presence of particular heterogeneous catalysts including at least one of platinum or gold. The metals are preferably provided on a support selected from the group of titania, stabilized titania, zirconia, stabilized zirconia, silica or mixtures thereof, most preferably zirconia stabilized with tungsten. The reaction with oxygen is carried out at a temperature from about 100° C. to about 300° C. and at a partial pressure of oxygen from about 50 psig to about 2000 psig.


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