The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 07, 2018

Filed:

Jun. 02, 2016
Applicant:

Scientific Design Company, Inc., Little Ferry, NJ (US);

Inventors:

Christelle Verrier, Little Ferry, NJ (US);

Wojciech L. Suchanek, Wyckoff, NJ (US);

Assignee:

Scientific Design Company, Inc., Little Ferry, NJ (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 21/04 (2006.01); B01J 21/08 (2006.01); B01J 21/12 (2006.01); B01J 23/04 (2006.01); B01J 23/36 (2006.01); B01J 23/50 (2006.01); B01J 35/10 (2006.01); B01J 19/00 (2006.01); C07D 301/10 (2006.01); B01J 37/00 (2006.01);
U.S. Cl.
CPC ...
B01J 21/04 (2013.01); B01J 19/0013 (2013.01); B01J 23/04 (2013.01); B01J 23/36 (2013.01); B01J 23/50 (2013.01); B01J 35/1009 (2013.01); B01J 35/1038 (2013.01); B01J 35/1042 (2013.01); B01J 35/1047 (2013.01); B01J 37/0018 (2013.01); C07D 301/10 (2013.01); B01J 2219/00051 (2013.01);
Abstract

A method is provided for improving the performance of a silver-based epoxidation catalyst comprising a carrier. The carrier includes at least 80 percent alpha alumina and has a pore volume from 0.3 mL/g to 1.2 mL/g, a surface area from 0.3 m/g to 3.0 m/g, and a pore architecture that provides at least one of a tortuosity of 7 or less, a constriction of 4 or less and a permeability of 30 mdarcys or greater. A catalytic amount of silver and a promoting amount of one or more promoters is disposed on and/or in said carrier. The method further includes the steps of initiating an epoxidation reaction by reacting a feed gas composition containing ethylene and oxygen present in a ratio of from about 3.5:1 to about 12:1, in the presence of the silver-based epoxidation catalyst at a temperature of about 200° C. to about 230° C., and subsequently increasing the temperature either stepwise or continuously.


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