The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 31, 2018

Filed:

Mar. 07, 2014
Applicant:

Tpc Group Llc, Houston, TX (US);

Inventors:

Clifford Alan Maat, Pearland, TX (US);

Joseph G. Duff, League City, TX (US);

Liana Caciula, Houston, TX (US);

Michael O. Nutt, Pearland, TX (US);

Robert Z. Confair, Friendswood, TX (US);

Mark P. Kaminsky, Friendswood, TX (US);

Jillian M. Horn, Houston, TX (US);

Gus K. Georgeton, Friendswood, TX (US);

Assignee:

TPC Group LLC, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 5/327 (2006.01); C07C 2/26 (2006.01); C07C 5/48 (2006.01); B01J 8/04 (2006.01); B01J 8/02 (2006.01); B01J 23/78 (2006.01); C07C 2/36 (2006.01);
U.S. Cl.
CPC ...
C07C 5/48 (2013.01); B01J 8/025 (2013.01); B01J 8/04 (2013.01); B01J 8/0419 (2013.01); B01J 8/0453 (2013.01); B01J 8/0492 (2013.01); B01J 8/0496 (2013.01); B01J 23/78 (2013.01); C07C 2/36 (2013.01); B01J 2208/00176 (2013.01); B01J 2208/00256 (2013.01); B01J 2208/00274 (2013.01); B01J 2208/00362 (2013.01); C07C 2523/745 (2013.01); C07C 2527/185 (2013.01); C07C 2527/187 (2013.01); C07C 2531/14 (2013.01); C07C 2531/24 (2013.01); Y02P 20/125 (2015.11);
Abstract

A method of oxidatively dehydrogenating a dehydrogenation reactant includes providing a first gaseous feed stream to a first adiabatic, catalytic reaction zone with less than a stoichiometric amount of oxygen and superheated steam, oxidatively dehydrogenating dehydrogenation reactant in said first adiabatic, catalytic reaction zone and subsequently cooling the effluent, adding additional oxygen and reacting the effluent stream in at least one subsequent adiabatic reaction zone. The dehydrogenation system enables higher conversion and yield per pass and in some cases greatly reduces steam usage and energy costs. In a preferred integrated process, ethylene is converted to n-butene which is then oxidatively dehydrogenated to butadiene.


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