The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 24, 2018

Filed:

Apr. 19, 2013
Applicant:

Archer Daniels Midland Company, Decatur, IL (US);

Inventor:

Oscar Suarez-Hernandez, Saint-Laurent, CA;

Assignee:

Archer Daniels Midland Company, Decatur, IL (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 20/26 (2006.01); B01J 20/22 (2006.01); B01J 20/32 (2006.01); B01J 20/30 (2006.01); C08J 3/24 (2006.01); C08J 7/04 (2006.01);
U.S. Cl.
CPC ...
B01J 20/267 (2013.01); B01J 20/223 (2013.01); B01J 20/3014 (2013.01); B01J 20/3078 (2013.01); B01J 20/3208 (2013.01); C08J 3/24 (2013.01); C08J 3/245 (2013.01); C08J 7/04 (2013.01); C08J 2333/02 (2013.01); C08J 2333/26 (2013.01); C08J 2403/06 (2013.01);
Abstract

A dual-surface treated composite superabsorbent particle comprising a polycarboxylate polymer (e.g., saponified polyacrylamide) and a carboxylated starch polymer is disclosed. The surface of the particle is cross linked through esterification with a C-Cpolyol exemplified with glycerol. In addition, the surface region is crosslinked through ionic bonds with a trivalent metal ion exemplified with aluminum. In a critical method of making, the acidification of the surface with the polyol occurs prior to treatment with the trivalent metal ion, which results is a hybrid particle that can include up to about 40% of carboxymethyl starch yet exhibit a FSC of at least 47 g/g, a CRC of at least 27 g/g, an AUL of at least 18 g/g under a load of 0.7 psi, and a SFR of at least 180 ml/min. Also disclosed is a method of making that includes a surface esterification prior to aluminum treatment.


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