The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 17, 2018

Filed:

Aug. 18, 2014
Applicant:

International Business Machines Corporation, Armonk, NY (US);

Inventors:

Dylan J. Boday, Tucson, AZ (US);

Jeannette M. Garcia, San Jose, CA (US);

James L. Hedrick, Pleasanton, CA (US);

Alshakim Nelson, San Carlos, CA (US);

Rudy J. Wojtecki, San Jose, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C09D 161/20 (2006.01); C08L 61/22 (2006.01); B29C 67/00 (2017.01); B33Y 70/00 (2015.01); C09D 125/06 (2006.01); C08J 5/04 (2006.01); C08G 12/06 (2006.01); C08G 12/08 (2006.01); C08J 5/24 (2006.01); B29K 79/00 (2006.01); B29L 31/00 (2006.01); B29K 61/00 (2006.01); B33Y 10/00 (2015.01);
U.S. Cl.
CPC ...
C08L 61/22 (2013.01); B29C 67/0051 (2013.01); B29C 67/0055 (2013.01); B33Y 70/00 (2014.12); C08G 12/06 (2013.01); C08G 12/08 (2013.01); C08J 5/04 (2013.01); C08J 5/24 (2013.01); C09D 125/06 (2013.01); B29K 2061/00 (2013.01); B29K 2079/00 (2013.01); B29L 2031/726 (2013.01); B33Y 10/00 (2014.12); C08J 2361/22 (2013.01);
Abstract

This application describes methods of forming an object. The methods described include forming a mixture with i) one or more primary diamines, ii) one or more polymerizable monomers, iii) a formaldehyde-type reagent, and iv) a polymerization initiator; forming a gel by heating the mixture to a temperature of at least 50° C.; and curing the one or more polymerizable monomers by activating the polymerization initiator. The one or more primary diamines may include one or more amine functional oligomers and/or primary aromatic diamine small molecules. The one or more polymerizable monomers may include styrenics, acrylates, methacrylates, vinyl esters, unsaturated polyesters, and derivatives thereof. The gel is a polyhemiaminal (PHA), a polyhexahydrotriazine (PHT), and/or a polyoctatriazacane (POTA) polymer, and curing of the gel forms an interpenetrating network of the PHA/PHT/POTA and the polymer formed from the polymerizable monomers.


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