Qingdao University of Technology

Qingdao Institute of Marine Geology

Zuquan Jin

Dongshuai Hou

Shaochun Li

Yongjuan Geng

Yunsheng Zhang

Bo Pang

Yong Yu

Xiaoying Zhang

Youlai Zhang

Yaguang Zhu

Xiaomei Wan

Peng Zhang

Xu Chen

Ben Mou

Cheng Liu

Tiejun Zhao

Bin Zhang

Mengyuan Li

Song Gao

Jianlin Luo

Pengfei Guo

Wenfeng Liu

Ziguo Wang

Yuyan Sun

Jigang Zhang

Ning Li

Yan Wang

Li Tian

Wanqiu Zhou

Rusheng Qian

Yidong Chen

Shilin Xu

Dafu Wang

Guoqing Geng

Heping Zheng

Ang Liu

Ruiyong Zhang

Qilong Xiao

Xiaoyun Song

Chuansheng Xiong

Fanxiu Chen

Weifeng Zhang

Dongyi Lei

Pengcheng Ren

Zhaoyi Chen

Xiaoqing Wang

Jihong Jiang

Jing Gao

Xueqing Zhu

Penggang Wang

Dehu Yu

Tao Yu

Siyao Guo

Yupeng Tian

Zhihang Pang

Provided is the use of a silane composite emulsion as an anti-cracking enhancer in a cement-based material. In the present disclosure, active groups on an isobutyltriethoxysilane molecule react with hydroxyl groups on a surface of a mortar to form a layered hydrophobic structure, slowing down a water loss inside the mortar of a cement-based material. The dehydration of butyl acrylate forms a network structure, which fills pores of the cement-based material, inhibits shrinkage of the cement-based material, and reduces the cracking caused by the shrinkage. Tetraethoxysilane can undergo hydrolysis at a room temperature to generate nano-silica with a large number of hydroxyl groups on a surface; and the nano-silica can undergo secondary hydration with calcium hydroxide in the cement to form a secondary hydration product C—S—H gel, thereby filling most of voids to make a structure of the cement hydration product denser, to increase a strength of the mortar.

Use of silane composite emulsion as anti-cracking enhancer

A frustum embedded fabricated composite protective structure is provided, including a restraint frame, a back plate, an infill block and a buffer block. The restraint frame is provided with a plurality of mounting holes matching with the shape of the infill block, the restraint frame is arranged on the back plate, the infill block is in a frustum shape. The buffer block and the infill block are installed in the mounting hole of the restraint frame, the buffer block is arranged on the smaller end of the infill block, and the infill block is wedged into the mounting hole of the restraint frame through a wedge surface mating. Because this protective structure is assembled by multiple restraint frames and infill blocks, under the prestress restraint of partition blocks, the damage range after penetration or explosion will be significantly reduced, and it can withstand multiple blows.

Frustum embedded fabricated composite protective structure

A concrete interface agent relates to the technical field of concrete surface protection, an ingredient of the concrete interface agent comprises 55 to 100 parts by weight of a nano-calcium salt solution and a nano-SiOprecursor, 0.1 to 0.4 parts by weight of a surfactant, 30 to 60 parts by weight of a silane coupling agent and 10 to 40 parts by weight of a polydimethylsilane, an ingredient of the nano-calcium salt solution comprises 2 to 5 parts by weight of a calcium hydroxide, 2 to 5 parts by weight of an acid catalyst and 200 to 500 parts by weight of an alcohol-based organic solvent, which can form a coating layer with higher hydrophobic angle on the concrete surface, reduce the water absorption of the concrete, and is not easy to crack after drying, which has more protective effect and longer service life than the existing TEOS interface agent.

Concrete interface agent

An underwater rapid repair material for marine steel structure comprises: 20 to 50 parts by weight of an alkali activation material, 3 to 12 parts by weight of a fast hardening waterborne polymer curing agent, 2 to 8 parts by weight of a fast hardening waterborne polymer precursor, 30 to 100 parts by weight of an aggregate, 1 to 5 parts by weight of an activator and 3 to 20 parts by weight of a water. The underwater rapid repair material provided by the present invention is not dispersed and segregated in water, with an initial setting time as low as 0.5 hours and a final setting time as low as 1.1 hours, after pouring 3 hours, the compressive strength and flexural strength can reach about 60 MPa and 10 MPa respectively, and has high bonding strength to steel and is not easy to fall off after solidification.

Underwater rapid repair material for marine steel structure

The present invention provides a graphene oxide-tetraethyl orthosilicate (TEOS)/silane composite gel material, and a preparation method and use thereof, and belongs to the technical field of building surface coating. The graphene oxide-TEOS/silane composite gel material provided by the present invention includes the following components: 5-45 parts by weight of graphene oxide dispersion, 30-90 parts by weight of TEOS, 30-80 parts by weight of silane, 1-5 parts by weight of emulsifier, and 1-5 parts by weight of dispersant; the graphene oxide dispersion has a concentration of 0.5-5%. The graphene oxide-TEOS/silane composite gel material provided by the invention can form a hydrophobic anticorrosive coating after coating the surface of a cement-based material, and has excellent water resistance and corrosion resistance.

Graphene orthosilicate/silane composite gel material, and preparation method and use thereof

A concrete curing agent, a curing coating layer and a preparation method thereof, the concrete curing agent comprises a hardening agent and a hydrophobic agent, the raw materials of the hardening agent comprises the following raw materials in parts by weight: 0.1-10 parts of fluorosilicate salt and 100 parts of water, and the hydrophobic agent comprises the following raw materials in parts by weight: 0.1-10 parts of a base catalyst, 1-10 parts of a silane coupling agent, 0.1-10 parts of hydrogen-containing silicone oil, 5-10 parts of a cross-linking agent, 10-100 parts of silica sol and 100-1000 parts of water. The present invention can significantly improve the strength, hardness and hydrophobicity, impermeability and freeze-thaw resistance of surface of concrete before and after hardening, and effectively improves the service life of concrete structures.

Concrete curing agent, curing coating layer and preparation method thereof

The present invention relates to a Z-type heterojunction photoanode film used for the photocathode protection of a reinforcing bar, the preparation method thereof and a method for the corrosion inhibition of mental materials from concrete structures in marine engineering by using the Z-type heterojunction photoanode film used for the photocathode protection of a reinforcing bar. The preparation method includes steps of preparing FeOon the conducting surface of a clean conductive substrate through the hydrothermal process, preparing FeO-PANI composite photoanode film by depositing polyaniline on the surface of FeOthrough the electrochemical synthesis and preparing Ru-FeO-PANI composite photoanode film on the surface of the FeO-PANI composite photoanode film through the in situ chemical reduction method. The technical solution in the present invention can achieve highly effective photocathode protection of a reinforcing bar from concretes in marine engineering and improve the durability of concrete structures in marine engineering.

Photoanode film for the photocathode protection and the durability improvement of a reinforcing bar in concretes, the preparation method thereof and a method of using the photoanode film for the photocathode protection and the durability improvement of a reinforcing bar in concretes

A carbon nanotube (CNT) assembled thin film modified steel wire array electrode, a preparation method and application thereof. The array electrode includes: a surface of a steel wire is negatively modified, and the surface of the steel wire is assembled with a plurality of layers of CNT thin films; one end of the steel wire is welded to a conductor, and a welding position between the steel wire and the conductor is wrapped with an insulating heat shrinkable tube; and the insulating template and the steel wire are encapsulated and cured by using an epoxy resin. The preparation method of the array electrode of the invention mainly includes the following steps: first, performing negative modification on a steel wire, then, assembling CNT thin films on the steel wire, and preparing the modified array steel wire into the CNT assembled thin film modified steel wire array electrode.

CNT assembled thin film modified steel wire array electrode, preparation method and application thereof

A superhydrophobic coating is provided and contains organosilane, an inorganic nanomaterial, and an emulsifying agent. A mass proportion of the components is controlled, so that the superhydrophobic coating can form a micro-nano mixed microstructure inside foam concrete. The organosilane first forms dense hydrophobic surface layers on the surface and in inner pores of the foam concrete, and the nanomaterial forms uniformly distributed nano-bulges on the hydrophobic surface layers formed by the silane. The superhydrophobic performance of the foam concrete can be effectively improved by combining the two microstructures. The foam concrete exhibits excellent superhydrophobic performance.

Superhydrophobic coating, superhydrophobic foam concrete, and preparation methods thereof

A life-cycle performance intelligent-sensing and degradation warning system and method for concrete structures are disclosed. The warning system comprises a main control module, a multifunctional sensor module, an anti-theft module and a critical warning module. Environmental parameters in concrete are monitored by the multifunctional sensor module, and the remaining service life of a concrete structure is accurately predicted through a life prediction model according to the temperature, humidity, chloride ion concentration and pH at different depths, and a critical chloride ion concentration and a structure stress status that are dynamically obtained. In addition, during warning analysis, a targeted correction method is designed for acquired data, and temperature and pH correction is carried out for real-time monitoring data of the chloride ion sensor to further guarantee the accuracy of monitoring data, such that scientific references are provided for durability evaluation, protection and restoration of the structure.

Life-cycle performance intelligent-sensing and degradation warning system and method for concrete structures

A method for measuring corrosion-expansion force during cracking of concrete due to corrosion and expansion of reinforcing steel; wherein, deformation on a surface of reinforced concrete is photographed based on a digital image correlation (DIC) method, a full-field displacement and a full-field strain on a surface of the concrete are analyzed and calculated, a relationship between corrosion-expansion force and the strain on the surface of the concrete is found through an established theoretical model, and corrosion-expansion force of reinforcing steel and a change rule of the corrosion-expansion force are calculated. Therefore, the method is simple and includes with safe and reliable operations, scientific principles, and low costs, so that a change in corrosion-expansion force during corrosion and expansion of reinforced concrete can be monitored in real time.

Method for measuring corrosion-expansion force during cracking of concrete due to corrosion and expansion of reinforcing steel

A double-steel tube concrete beam-column joint with internal FRP bar connectors is provided. The double-steel tube concrete beam-column joint includes double-steel tube columns, I-beams, a joint connector, an internal support member and external ring plates. Each double-steel tube column includes an internal steel tube and an external steel tube. The joint connector includes an internal connecting tube and an external connecting sleeve which are both circular steel tubes. The internal support member is a columnar structure and has two ends regularly formed with bolt holes in a circumferential direction. Each external ring plate comprises a horizontal portion and an annular portion perpendicular to the horizontal portion. Upper and lower double-steel tube columns are connected through the joint connector and the internal support member, the two ends of the internal support member are inserted into an upper internal steel tube and a lower internal steel tube, respectively.

Double-steel tube concrete beam-column joint with internal fiber reinforced polymer (FRP) bar connectors and assembly method

The present invention relates to the field of building surface coating technologies, and in particular, to an alumina sol-silane composite material and a preparation method and application thereof. The alumina sol-silane composite material provided in the present invention is prepared by raw materials including the following components by weight parts: 5 to 45 parts of alumina sol, 30 to 90 parts of silane, 3 to 10 parts of silane coupling agent, and 1 to 5 parts of dispersant. A hydrophobic anticorrosive coating can be formed after coating the alumina sol-silane composite material provided in the present invention to a surface of a cement-based material, and has good waterproof performance and corrosion resistance.

Alumina sol-silane composite material and preparation method and application thereof

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Qingdao, China

Zuquan Jin