Amprius, Inc.

Apple Inc.

Amprius Technologies, Inc.

Zuqin Liu

Song Han

Ghyrn E Loveness

Rainer Johannes Fasching

Constantin Ionel Stefan

Jonathan Bornstein

Weijie Wang

William S Delhagen

William S DelHagen

Richard M Mank

Hongli Dai

Ji-Guang Zhang

Wu Xu

Shabab Amiruddin

Xiaolin Li

Qiuyan Li

Ran Yi

Chongmin Wang

Hyea Kim

Sunho Kang

Rajankumar L Patel

Hyung-Seok Lim

Langli Luo

Yang He

Rainer J Fasching

Provided are examples of electrochemically active electrode materials, electrodes using such materials, and methods of manufacturing such electrodes. Electrochemically active electrode materials may include a high surface area template containing a metal silicide and a layer of high capacity active material deposited over the template. The template may serve as a mechanical support for the active material and/or an electrical conductor between the active material and, for example, a substrate. Due to the high surface area of the template, even a thin layer of the active material can provide sufficient active material loading and corresponding battery capacity. As such, a thickness of the layer may be maintained below the fracture threshold of the active material used and preserve its structural integrity during battery cycling.

Template electrode structures for depositing active materials

Provided herein are nanostructures for lithium ion battery electrodes and methods of fabrication. In some embodiments, a nanostructure template coated with a silicon coating is provided. The silicon coating may include a non-conformal, more porous layer and a conformal, denser layer on the non-conformal, more porous layer. In some embodiments, two different deposition processes, e.g., a PECVD layer to deposit the non-conformal layer and a thermal CVD process to deposit the conformal layer, are used. Anodes including the nanostructures have longer cycle lifetimes than anodes made using either a PECVD or thermal CVD method alone.

Structurally controlled deposition of silicon onto nanowires

The disclosed technology relates to a battery utilizing a dampening layer to prevent a failure of the battery. The battery includes an enclosure, a set of electrodes enclosed within the enclosure, and a dampening layer disposed within the set of electrodes. The dampening layer partitions the set of electrodes into a first subset of electrodes and a second subset of electrodes. The dampening layer is configured to absorb a mechanical impact on the enclosure to prevent a failure of at least one of the first subset of electrodes and the second subset of electrodes. The dampening layer may be formed at least one of a polymer, metal, and ceramic.

Dampening layers disposed within battery cell

An anode active material comprises a silicon-carbon secondary particle comprising a composite having an exterior conformal carbon coating and formed of type I primary particles. Each type I primary particle comprises a core particle of interconnected silicon, the interconnected silicon formed of nano-sized silicon particles each connected to at least one other particle, inner pores internal to the core particle and defined by the interconnected silicon, an internal carbon coating on internal wall surfaces of the inner pores and a conformal carbon coating on the core particle.

Interconnected silicon porous structure for anode active material

Provided herein are novel template electrode materials and structures for lithium ion cells. Related methods are also provided. According to various embodiments, an electrode can include a nanostructured template, an electrochemically active material layer coating the template, and a first intermediate layer between the nanostructured template and the electrochemically active material layer. In one arrangement, the nanostructured template includes silicide nanowires. The electrochemically active material may be any of silicon, tin, germanium, carbon, metal hydrides, silicides, phosphides, and nitrides. The first intermediate layer may facilitate adhesion between the nanostructured template and the electrochemically active material layer, electronic conductivity within the electrode, and/or stress relaxation between the nanostructured template and the electrochemically active material layer.

Template electrode structures with enhanced adhesion characteristics

Provided are battery electrode structures that maintain high mass loadings (i.e., large amounts per unit area) of high capacity active materials in the electrodes without deteriorating their cycling performance. These mass loading levels correspond to capacities per electrode unit area that are suitable for commercial electrodes even though the active materials are kept thin and generally below their fracture limits. A battery electrode structure may include multiple template layers. An initial template layer may include nanostructures attached to a substrate and have a controlled density. This initial layer may be formed using a controlled thickness source material layer provided, for example, on a substantially inert substrate. Additional one or more template layers are then formed over the initial layer resulting in a multilayer template structure with specific characteristics, such as a surface area, thickness, and porosity. The multilayer template structure is then coated with a high capacity active material.

High-capacity electrodes with active material coatings on multilayered nanostructured templates

Provided are novel electrode material composite structures containing high capacity active materials formed into porous base structures. The structures also include shells that encapsulate these porous base structures. During lithiation of the active material, the shell mechanically constrains the porous base structure. The shell allows lithium ions to pass through but prevents electrolyte solvents from interacting with the encapsulated active material. In certain embodiments, the shell contains carbon, while the porous base structure contains silicon. Although silicon tends to swell during lithiation, the porosity of the base structure and/or void spaces inside the shell helps to accommodate this additional volume within the shell without breaking it or substantially increasing the overall size of the composite structure. This allows integration of the composite structures into various types of battery electrodes and cycling high capacity active materials without damaging the electrodes' internal structures and deteriorating cycling characteristics of batteries.

Composite structures containing high capacity porous active materials constrained in shells

Batteries having improved current collection are provided. In some implementations, an electrode structure of a battery may include an active material and two or more current collectors in electrical communication with the active material. In some implementations, an electrode structure of a battery may include two or more current collector layers. According to various implementations, the electrode structure may or may not include a current collector substrate. In some implementations, a battery anode includes a current collector substrate in electronic contact with nanostructured active material. In order to ensure that electronic communication between the active material and the current collector substrate is maintained throughout the life of the battery, a second electronically conductive path is provided in the form of a current collector layer over the nanostructured active material. The additional layer is thin and electronically conductive, and does not interfere adversely with battery operation.

Dual current collectors for battery electrodes

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Sunnyvale, CA, United States of America

Zuqin Liu