Beijing University of Technology

Zuoren Nie

Xiaoli Xi

Hui Huang

Liwen Ma

Kunyuan Gao

Shengping Wen

Rui Shao

Wenxia Ru

Xiaokai Sun

Zhengzheng Zhang

A method for separating nickel and cobalt from a solution includes the steps of: obtaining a solution containing nickel and cobalt by acid leaching of a cathode material of a waste lithium-ion battery, adjusting the pH of the solution containing nickel and cobalt to 3.5 to 4.5, adding extractants for extraction to separate the nickel and the cobalt. The cobalt enters the organic phase, the nickel remains in the aqueous phase, and the extractants contain an acidic extractant and an alkaline extractant. The method for efficiently separating nickel and cobalt through extraction adopts a non-saponification extraction method without using NaOH as a saponifier, thereby avoiding the discharge of saponification wastewater. Under acidic conditions, the cobalt in an acidic leaching solution is effectively extracted and separated into the organic phase through synergistic action of the acidic extractant and the alkaline extractant, thereby realizing the separation of nickel from cobalt.

Method for separating nickel and cobalt from a solution

The present invention provides a process for recycling waste carbide, wherein the waste carbide is directly used as anode and electrolyzed in the molten salt, comprising the following steps: 1) the vacuum dehydrating of the molten salt electrolyte; 2) electrolyzing the waste carbide, which is used as anode, and an inert electrode, which is used as cathode in the molten salt electrolyte with the electrolysis temperature of 350&#x2dc;1000&#xb0; C.; 3) separating and collecting the metal powder obtained by electrolysis from molten salt medium. According to the technical solutions of the present invention, tungsten and cobalt ions can be dissolved from the anode material-waste carbide directly into the molten salt medium and deposited on the cathode plate with being driven by the electrolysis voltage, to obtain the metal powder particles. The tungsten, cobalt and other products obtained by electrolysis can be used as carbide materials, high temperature structural materials, weapons materials, photocatalytic materials, etc., and can be applied to the fields of processing production, aerospace, military industry, environment and energy, and the like. This method has a short process, has no solid/liquid/gas waste emissions, and is environment-friendly.

Process for recycling waste carbide

A kind of aluminum alloy and corresponding heat treatment process applied to manufacturing aluminum/steel cladding plates which are resistant to high temperature brazing belong to alloy materials technology field. In the aluminum/steel cladding plates, the aluminum part was alloyed with 0.76%&#x2dc;0.78% Si and 0.055&#x2dc;0.10% Er in weight percent and the rest was Al and some unavoidable impurity. The Steel part was 08Al steel. After cladding cold rolling with deformation of 55%&#xb1;2%, the aluminum/steel cladding plates were annealed at 510&#x2dc;535&#xb0; C. for different times. Then simulated brazing process was performed to optimize the range of annealing time and temperature. The so produced Al/St cladding plates could not only effectively solve the low interface strength in Al/St cladding plates, but also meet the mechanical properties which were necessary for further processing of Al/St cladding plates. It was provided a kind of aluminum alloy and corresponding heat treatment process which could effectively solve the low bonding strength under the condition of high temperature brazing because of the existence of brittle Fe&#x2014;Al phases.

Aluminum alloy and corresponding heat treatment process applied to manufacture aluminum/steel cladding plates resistant to high temperature brazing

The present invention relates to a process for efficiently enriching and recovering noble metals of platinum and palladium based on solvent extraction, wherein isoamyl alcohol is used as extracting agent and 2-methoxyphenyl thiourea is used as extraction-assisted complexing agent. 2-methoxy-phenyl thiourea is added to aqueous phase to react with platinum and palladium, and isoamyl alcohol is used as extracting agent to extract the organic phase, thus realizing the purpose of separating and extracting noble metals from base metals while enriching noble metals of platinum and palladium. The present invention, which can not only realize the separation of noble metals and base metals, but also enhance the enrichment and recovery ratios of noble metals of platinum and palladium, with low cost reagents, small influence on the environment and simple technical process, thus is a new and efficient extraction and enrichment system for noble metals.

Process for efficiently enriching and recovering noble metals of platinum and palladium by solvent extraction

A heat treatment process of high-Mg Er-containing aluminum alloy cold-rolled plates resistant to intergranular corrosion is disclosed, which belongs to the field of non-ferrous metals. The mass percentage of each component of high-Mg Er-containing aluminum alloy heat-rolled plates is, respectively, 5.8%-6.8% of Mg, 0.4%-0.8% of Mn, 0.15%-0.25% of Er, 0.15%-0.25% of Zr, the unavoidable impurities content being less than 4%, the balance being Al. The alloy hot-rolled plates are cold-rolled until the final cold deformation being 75%-90% after the intermediate annealing; the aluminum alloy cold-rolled plates undergo a stabilization annealing at the annealing temperature of 235&#xb0; C. to 245&#xb0; C. for 3.5-4 hours, and then is cooled in air to room temperature. This process significantly improves the resistance to intergranular corrosion while it does not reduce the strength of the alloy significantly.

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Beijing, China

Zuoren Nie