Tianfu Yongxing Laboratory

Southwest Petroleum University

Zijia Liao

Jinzhou Zhao

Wanfen Pu

Chao Shen

Daijun Du

Bo Zhou

Rui Jiang

Shuai Zhao

Ying Xiong

Zezhou Fang

Jintao Li

Qingyuan Chen

Xiaodong Tang

Su Liu

Ziyuan Yi

The present invention discloses a supercritical CO2 thickener for shale gas reservoir based on hollow mesoporous silica nanoparticles and a preparation method thereof, and relates to the technical field of oil and gas field development. The preparation method of the thickener includes: reacting a monomer consisting of fluoroacrylate, styrene and vinyl acetate in a molar ratio of 3-5:1-2:1-2 with 2%-5% of a total weight of hollow mesoporous silica nanoparticles with carbon-carbon double bonds under the action of an initiator to obtain the thickener. The preparation method of the present invention does not involve the addition of organic solvents during the reaction process and thus does not cause harm to the human body. The thickener of the present invention has good CO2 viscosity-increasing effect and good sand carrying performance, and can effectively improve the fracturing effect.

Supercritical CO2 thickener for shale gas reservoir based on hollow mesoporous silica nanoparticles and preparation method thereof

A displacement system designed for robust heterogeneous oil reservoirs and its application within the oil exploitation field. System comprises a polymer-enhanced foam plugging agent and an active polymer flooding agent. Plugging agent consists of 0.12% bio-polysaccharide polymer diutan gum foam stabilizer and 0.4% α-olefin sulfonate foaming agent by mass. The active polymer flooding agent is formulated through free radical polymerization, with components comprising a total monomer concentration of 27.5%, wherein monomer A to monomer B ratio is 7.5:2.5, monomer C constitutes 5.5% of the total monomer concentration, and water comprises the remaining. Monomer A is acrylamide, monomer B is 2-acrylamide-2-methyl propane sulfonic acid, and monomer C is a quaternary ammonium salt type active monomer. Demonstrated through parallel core displacement experiments, this displacement system exhibits effective displacement in heterogeneous oil reservoirs with a permeability gradation of 30 at 65° C., significantly enhancing oil recovery rates in robust heterogeneous oil reservoirs.

Displacement system suitable for strong heterogeneous oil reservoir and its application

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Chengdu, China

Zijia Liao