China Petroleum Chemical Corporation

Research Institute of Nanjing Chemical Industry Group

Research Institute of Nanjing Chemical Industrial Group

Zhongbin Huang

Songbai Mao

A carbon dioxide absorbent is disclosed. The absorbent comprises organic amine, amino acid, and water, wherein said organic amine comprises tertiary amine and primary amine and/or secondary amine; and wherein amino acid is excess based on a stoichiometrical ratio of organic amine to amino acid in a reaction. A method for absorbing and desorbing carbon dioxide is further disclosed. In the absorbent system provided by the present disclosure, the conversion between primary (secondary) amine and (secondary) tertiary amine can be realized under the catalytic effect of amino acid with the changing of temperature, and carbon dioxide can be absorbed and desorbed effectively under a relatively low temperature.

Carbon dioxide absorbent and method for absorbing and desorbing carbon dioxide

An organic amine decarbonization solution includes: i) one or more organic amines serving as a carbon dioxide absorbent; and ii) an antioxidant. The antioxidant includes: a) one or more organometallic complexes of Formula [M(L)]A, wherein each M independently represents a central atom selected from the group consisting of transition metals, Group IVA metals and Group VA metals at a lower valence state; each L independently represents a bidentate or multidentate organic ligand with each ligating atom thereof being independently one of O, S, N and P; each A independently represents an uncoordinated counter-ion suitable for forming an outer sphere of a complex; x is 1, 2 or 3; y is 1, 2, 3, 4, 5, 6, 7 or 8; and n is 0, 1, 2, 3 or 4; and b) optionally one or more metal chelating agents.

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Nanjing, China

Zhongbin Huang