United States of America, As Represented by the Secretary of Agriculture

Other

Wisconsin Alumni Research Foundation

Mississippi State University

Domtar Paper Company, LLC

Zhiyong Cai

Qiangu Yan

Jinghao Li

Shaoqin Gong

Xudong Wang

Qifeng Zheng

Chunhua Yao

Jilei Zhang

Bruno S Marcoccia

Ronald Sabo

Alberto Hernandez

Yanhao Yu

Zhaodong Li

Alireza Javadi

James David Freiberg

Bruno Sisto Marcoccia

Methods of forming a carbon fiber reinforced carbon foam are provided. Such a method may comprise heating a porous body composed of a solid material comprising covalently bound carbon atoms and heteroatoms and having a surface defining pores distributed throughout the solid material, in the presence of an added source of gaseous hydrocarbons. The heating generates free radicals in the porous body from the heteroatoms and induces reactions between the free radicals and the gaseous hydrocarbons to form covalently bound carbon nanofibers extending from the surface of the solid material and a network of entangled carbon microfibers within the pores the porous body, thereby forming a carbon fiber reinforced carbon foam. Carbon fiber reinforced carbon foams and ballistic barriers incorporating the foams are also provided.

Carbon fiber reinforced carbon foams

Methods of making self-expended lignofoams are provided. In embodiments, such a method comprises exposing a self-expanding lignofoam composition comprising raw lignin and a thermoplastic polymer to an elevated temperature for a period of time to soften the composition, desorb water from the raw lignin or induce at least some hydroxyl groups of the raw lignin to undergo dehydration reactions to generate water or both, vaporize the water, and generate pores throughout the softened composition. The method further comprises cooling the porous, softened composition to room temperature to provide the self-expanded lignofoam. The self-expanding lignofoam composition is free of an added plasticizer, an added lubricant, an added foaming agent, and an added blowing agent, and the thermoplastic polymer is not a starch, not a polyurethane, and not a polysiloxane. The resulting self-expanded lignofoams are also provided.

Self-expanding lignofoam compositions and lignofoams made therefrom

A method of making a carbon foam comprises subjecting a precursor composition comprising an amount of at least partially decomposed lignin to a first pressure for a first time, optionally, while heating the precursor composition to a first temperature; heating the compressed precursor composition to a second temperature for a second period of time while subjecting the compressed precursor composition to a second pressure to further decompose the at least partially decomposed lignin and to generate pores within the compressed precursor composition, thereby providing a porous, decomposed precursor composition; and heating the porous, decomposed precursor composition to a third temperature for a third time to carbonize, and optionally, to graphitize, the porous, decomposed precursor composition to provide the carbon foam. Also provided are the carbon foams and composites made from the carbon foams.

Lignin-based carbon foams and composites and related methods

A method of synthesizing a graphene-based material comprises exposing graphene-encapsulated metal nanoparticles, each nanoparticle comprising a graphene shell surrounding a metal core, to a cracking and welding gas composition under conditions sufficient to crack graphene shells and to reconstruct cracked graphene shells to form the graphene-based material.

Method for synthesizing graphene from encapsulated particles

Highly porous, lightweight, and sustainable organosilane-coated organic aerogels with ultra-low densities and excellent material properties and methods for preparing them are provided. The aerogels are modified to have a superhydrophobic and superoleophilic surface, thus leading to an extremely high affinity for oils and/or organic solvents.

Sustainable aerogels and uses thereof

Triboelectric nanogenerators that operate in a vertical contact separation mode and methods for fabricating the triboelectric generators are provided. Also provided are methods for using the triboelectric nanogenerators to harvest mechanical energy and convert it into electric energy. In the TENGs, one or both of the triboelectrically active layers comprises a cellulose that has been chemically treated to alter its electron affinity.

Triboelectric nanogenerators based on chemically treated cellulose

Photocatalytic structures having a capillary-force based electrolyte delivery system are provided. Also provided are photoelectrochemical and photocatalytic cells incorporating the structures and methods for using the cells to generate hydrogen and/or oxygen from water. The photocatalytic structures use an electrolyte-transporting strip comprising a porous network of cellulose nanofibers to transport electrolyte from a body of the electrolyte to a porous photoelectrode or a porous photocatalytic substrate via capillary force.

Capillary photoelectrode structures for photoelectrochemical and photocatalytic cells

Highly porous, lightweight, and sustainable hybrid organic aerogels with ultra-low densities and excellent material properties and methods for preparing them are provided, including, e.g., PVA/CNF/GONS, RF/CNF/GONS, and PVA/CNF/MWCNT. The aerogels are modified to have a super-hydrophobic surface, thus leading to an extremely low swelling ratio and rate of moisture absorption.

Sustainable hybrid organic aerogels and methods and uses thereof

Embodiments of the presently-disclosed subject matter include methods for synthesizing carbon nanomaterials from a lignin and/or source thereof. Exemplary methods comprise a process of thermal treating a lignin and/or source thereof in the presence of a catalyst to synthesize graphene nanosheets.

Methods for synthesizing graphene from a lignin source

The teachings provided herein are generally directed to a non-destructive method of measuring a moisture content profile across a dimension of a hygroexpansive, composite material using radiation and a volumetric shrinkage correction. The measurement of a series of moisture content profiles over time can provide, for example, a measure of the movement of moisture during the process of drying of the composite material.

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Madison, WI, United States of America

Zhiyong Cai