Chinese Academy of Sciences

Zhiyang Chen

Zhongmin Liu

Yong Liu

Wenliang Zhu

Hongchao Liu

Youming Ni

Shiping Liu

Xiangang Ma

A method for directly preparing p-xylene from synthetic gas and aromatic hydrocarbon. The method includes contacting the feedstock containing synthetic gas and aromatic hydrocarbon excluding p-xylene with the catalyst in the reaction zone under reaction conditions sufficient to convert at least part of the feedstock to obtain a reaction effluent containing p-xylene; and separating p-xylene from the reaction effluent, where the catalyst includes a highly dispersed metal oxide material confined by an inert carrier, an acidic molecular sieve, and optionally at least one of graphite powder and dispersant, where in the highly dispersed metal oxide material confined by the inert carrier, the inert carrier is at least one of silicon oxide and alumina, and the content of the metal oxide in terms of metal is less than or equal to 10% by mass calculated based on the weight of the highly dispersed metal oxide material confined by the inert carrier.

Method for directly preparing p-xylene from synthetic gas and aromatic hydrocarbon

A catalyst for synthesizing aromatic hydrocarbons, a preparation method thereof and a method for synthesizing aromatic hydrocarbons by using the catalyst. The catalyst comprises acidic molecular sieve particles and zinc-aluminum composite oxide particles. The catalyst has relatively high selectivity to aromatic hydrocarbons, particularly BTX, stable performance, and a long single-pass life.

Catalyst for synthesizing aromatic hydrocarbons and preparation method therefor

Disclosed is a method for preparing aromatic hydrocarbons, particularly relates to the preparation of the aromatic hydrocarbons by passing methanol and carbon monoxide through a reactor loaded with an acidic ZSM-5 molecular sieve catalyst containing no metal additive under reaction conditions. Compared with the prior art, the method provided by the present invention can improve and stabilize the selectivity to aromatic hydrocarbons, particularly BTX, by adding carbon monoxide in methanol aromatization, and also prolongs the single-pass life of the catalyst. The performance of an inactivated catalyst is not significantly degraded after repeated regenerations. Furthermore, the catalyst preparation process omits the step of adding a metal additive, so that not only the process is simplified, but also costs are greatly reduced, and environmental protection is facilitated.

Method for preparing aromatic hydrocarbons

A method for preparing aromatics from syngas, which includes a) contacting a raw material stream containing syngas with a catalyst in a reaction zone under reaction conditions sufficient to convert at least part of the raw material to obtain a reaction effluent; b) separating the reaction effluent to obtain at least a recycle stream containing gas-phase hydrocarbons having 1 to 4 carbon atoms and unconverted syngas and a liquid stream containing hydrocarbons having 5 or more carbon atoms; c) returning the recycle stream to the reaction zone; and d) separating aromatic products from the liquid stream, wherein the catalyst includes at least one of an inert carrier-confined highly dispersed metal oxide material, an acidic molecular sieve, and, optionally, graphite powder and a dispersant.

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Dalian, China

Zhiyang Chen