China Petroleum Chemical Corporation

Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation

Petrochina Company Limited

Tsinghua University

Zhixiang Zhang

Jinbing Li

Jianshe Chen

Wei Lin

Jun Jiang

Qian Xue

Shujuan Wang

Shuyuan Cao

Qiang Lin

Xianming Xu

Xianfeng Li

Fangwei Li

Wei Zhang

Hui Wang

Guizhi Wang

Lixin Gao

Yong Jin

Jianzhong Li

Yinghui Li

Huimin Yuan

Fengrong Wang

Guoquan Song

Haotian Pei

Kezhong Xu

Xiangmin Yu

Xiangju Meng

Qunying Zeng

Fujian Liu

Shuyun Li

Yueman Li

Haicheng Xiao

Fengshou Xiao

Wenpeng Li

Wujun Dai

Zhiqiang Tang

Dawei Zhang

Lijun Liu

Jina Zhao

Jing Wei

Fengbo Ma

Shubao Wan

Xuli Zhai

Zhongtao Zhang

Rujun Liang

Xinxin Sun

The present disclosure discloses an &#x3b1;-alumina carrier, comprising the elements of lanthanum and silicon both dispersed in the interior and on the surface of the carrier. The mass ratio of the element of lanthanum to the element of silicon is in the range from 0.1:1 to 20:1. The inventors of the present disclosure have made extensive researches into the field of the silver catalyst and alumina carrier thereof, and added the elements of lanthanum and silicon (i.e., bulk phase addition) in preparing the alumina carrier used in the silver catalyst. The carrier thus obtained contains the elements of silicon and lanthanum both in the interior and on the surface thereof, and has improved specific surface area and strength. The silver catalyst prepared with the carrier can react in a low reaction temperature (has a high reaction activity) and has a high selectivity in producing ethylene oxide through oxidation of ethylene.

Alumina carrier, method of preparing the same, and silver catalyst

A method for preparing catalyst coating on a metal base plate comprising: thermal-spraying a layer of &#x3b1;-aluminum oxide nano-particles on a metal base plate using a high temperature flame powder spray gun, at a temperature of 2500-3500&#xb0; C. and a pressure of 0.2-1.2 MPa; coating an aluminum sol, the weight concentration of the aluminum sol aqueous solution being 2-30%, at a pH of 0.5-4, the drying temperature being 50-150&#xb0; C., the drying time being 0.5-24 hours, the calcination temperature being 200-1200&#xb0; C., and the calcination time being 0.5-24 hours; immersing in an active component, the immersing temperature being 20-120&#xb0; C., the duration being 0.5-24 hours, the drying temperature being 50-150&#xb0; C., the drying time being 0.5-24 hours, the calcination temperature being 200-1200&#xb0; C., and the calcination time being 0.5-24 hours. The method is suitable for the preparation of various catalyst coatings with active components.

Method for preparing catalyst coating on metal base plate

The present invention relates to an alumina support for silver catalyst, a process for preparing said alumina support, a silver catalyst made from said alumina support, and a use of said silver catalyst in the production of ethylene oxide by the oxidization of ethylene. According to the present invention, the silver catalyst made from the support prepared by potassium melt technology can have a high selectivity.

Alumina support for silver catalyst, preparation and use thereof

The present invention discloses an alumina carrier for a silver catalyst, a process for preparing the alumina carrier, a silver catalyst made from the alumina carrier, and a use of the silver catalyst in the production of ethylene oxide by the oxidization of ethylene. The alumina carrier comprises alumina and promoters, as well as titanium silicate molecular sieve(s); and therefore, has an improved catalytic activity.

Carrier for silver catalyst, its preparation, a silver catalyst made from the same and its use

The invention relates to a catalyst for the catalytic esterification and acylation reaction. The catalyst is prepared by the steps of adding a divinyl benzene monomer into a solvent prepared by mixing azobisisobutyronitrile, tetrahydrofuran and water, performing hydrothermal treatment at the normal temperature under the constant pressure, and volatilizing the solvent at the room temperature to obtain polydivinylbenzene; grinding the polydivinylbenzene into 200-mesh powder and performing degassing treatment under the nitrogen condition; adding polydivinylbenzene blocks into 1,1',2-trichloroethane to explode and crack into small blocks, wherein the small blocks swell; evenly mixing 1,1&#x2032;,2-trichloroethane and concentrated sulfuric acid, adding silver sulfate serving as a catalyst, adding processed polydivinylbenzene, performing sulfonation, filtering and washing with dioxane and water till it is neutral, performing drying, using dilute sulphuric acid to activate, performing washing till the it is neutral and performing drying. The catalyst has high catalytic activity and conversion rate.

Use of organic framework porous solid acid

The present invention relates to a support for silver catalyst used in the ethylene oxide production, a preparation method for the same, a silver catalyst prepared from the same, and its use in the ethylene oxide production. The silver catalyst produced from the silver catalyst support has an improved activity, stability and/or selectivity in the production of ethylene oxide by epoxidation of ethylene.

Support for silver catalyst in ethylene oxide production, methods for preparing the same, silver catalyst prepared therefrom, and use thereof

An alumina support comprises alpha-alumina as the main crystal phase of its backbone, and having a specific surface area of no higher than 3.0 m/g, a pore volume ranging from 0.3 ml/g to 0.8 ml/g, an alkaline earth metal content ranging from 0.05% to 2.0% by weight of the support, wherein the support has such properties that treating the support with an aqueous oxalic acid solution having a concentration ranging from 0.4% to 2.0% by weight and having twice the weight of the support for 30 minutes can produce a leach liquor having an aluminum content of no higher than 60 &#x3bc;g/mL, a sodium content of no higher than 20 &#x3bc;g/mL, and a silicon content of no higher than 40 &#x3bc;g/mL. Processes for preparing the alumina support, silver catalysts comprising the alumina support, and methods of preparing ethylene oxide by ethylene oxidation using the silver catalyst are also disclosed herein.

Alumina support, a process for preparing the support, a silver catalyst prepared from the support, and use thereof

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Beijing, China

Zhixiang Zhang