Tongji University

Tianjin Polytechnic University

Lexvu Opto Microelectronics Technology (shanghai) Ltd

Shanghai Jadic Optoelectronics Technology Co., Ltd

Zhiwei Wang

Ruobin Dai

Xueye Wang

Jianhong Mao

Hongwei Zhang

Zhichao Wu

Lei Zhang

Deming Tang

Mei Chen

Tianlin Wang

Jie Wang

Liang Wang

Fengqin Han

Qiaoying Wang

Wei Shi

Chen Pan

Hongyi Han

Chenxin Tian

Huimin Zhou

Wenfen Chang

Yue Wen

Zimeng Li

Yingqing Chen

Kaili Yan

Xingran Zhang

Jiayi Li

Yanqiang Ma

Junjian Zheng

Jiansuxuan Chen

Lijun Meng

The present disclosure relates to a layered bimetallic hydroxide-based hydrogel bipolar membrane and a method for preparing the same. The method includes: blade-coating a quaternized polyethersulfone solution on a substrate, and carrying out drying to obtain an anion exchange layer; immersing the layer sequentially and cyclically in a sodium alginate solution and a first metal ion mixed solution to obtain a hydrogel anion exchange membrane; immersing the hydrogel membrane sequentially in a second metal ion mixed solution and an alkaline solution; and blade-coating a sulfonated polyethersulfone solution on the obtained membrane, and carrying out drying to obtain the layered bimetallic hydroxide-based hydrogel bipolar membrane. The anion and cation exchange membrane layers on two sides of the bipolar membrane prepared in the present disclosure are closely bound by way of hydrogel cross-linking. The bipolar membrane has the advantages of high water dissociation efficiency, low energy consumption, and good stability.

Layered bimetallic hydroxide-based hydrogel bipolar membrane and method for preparing same

Provided is a high permeance nanofiltration membrane with nanoring-like structure and preparation method thereof. The membrane includes a base film and a polyamide layer having nanoring-like structure morphology on its surface. The method includes: (1) formulating a piperazine nanoemulsion containing a surfactant, vegetable oil, piperazine and water; and (2) infiltrating a base film with the piperazine nanoemulsion, and removing excess droplets from the surface of the base film to obtain a treated base film; covering the surface of the treated base film with a solution of trimesoyl chloride in n-hexane to perform interfacial polymerization; and drying the resulting membrane. Introduction of nano-oil droplets into aqueous phase as templates to construct nanoring-like structure morphology on the surface of the polyamide layer significantly increases the specific surface area and free volume of the polyamide layer without losing the salt rejection rate of the membrane, thereby greatly improving its water permeance.

High permeance nanofiltration membrane with nanoring-like structure and preparation method thereof

A method for recycling a scrapped polyvinylidene fluoride (PVDF) membrane through chemical cleaning-structural transformation-hydrophilicity is disclosed, which can extend the service life of scrapped PVDF membrane materials (namely, membrane at the end of service life). The method includes the following steps: cleaning a scrapped membrane with sodium hypochlorite and citric acid; treating the membrane with a structural transformation agent, where, irreversible contaminants are washed away while the PVDF membrane is subjected to pore expansion and hydrophilization; and with self-polymerization of dopamine on a membrane surface, further improving the hydrophilicity of the membrane surface, enhancing the anti-contamination performance, and repairing damaged points on the surface of the scrapped PVDF membrane produced during long-term operation.

Method for recycling scrapped polyvinylidene fluoride (PVDF) membrane produced in water treatment

A zeolite membrane and a preparation method thereof are provided. The method includes: adding an organic binder solution dropwise to zeolite, and thoroughly grinding and stirring; blade-coating a resulting mixture on a substrate at a given thickness; and drying to obtain the zeolite membrane. The preparation of a zeolite membrane does not require a complicated hydrothermal crystal growth process, and the membrane can be prepared directly from natural zeolite or artificial zeolite. A prepared zeolite membrane has the characteristics of simple preparation process, low cost, prominent water permeability, high contaminant rejection rate and high zeolite load. The zeolite membrane, when used for the rejection of contaminants in water, can not only remove macromolecular contaminants in water, but also efficiently remove ammonia nitrogen by way of ion exchange, which is suitable for advanced treatment of wastewater.

Zeolite membrane and preparation method thereof

A device for decomplexation and enhanced removal of copper based on self-induced Fenton-like reaction constructed by electrochemistry coupled with membrane separation is disclosed. The device includes a reactor, two electrocatalytic anodes capable of generating hydroxyl radicals, an electrocatalytic cathode membrane assembly, a direct current power supply, an aeration system, an inlet pipe and an outlet pipe. The device of the present invention has a simple construction. Using this device to treat industrial wastewater containing copper complexes under specific conditions allows the decomplexation and the removal of the industrial wastewater containing the copper complexes to be simultaneously realized at a low consumption and a high efficiency. The coupling of electrochemistry with membrane separation can be achieved to protect the cathode from being contaminated by pollutants in the sewage and prolong the service life of the electrode.

Device for decomplexation and enhanced removal of copper based on self-induced fenton-like reaction constructed by electrochemistry coupled with membrane separation, and use thereof

A polyamide (PA) nanofiltration (NF) membrane and a preparation method thereof by regeneration from a scrapped microfiltration (MF) membrane are provided. The method adopts a cleaning-repairing-interfacial polymerization upgrading strategy, where, sodium hypochlorite and oxalic acid are used for deeply cleaning a scrapped MF membrane. PDA is used as a repairing agent to construct a reaction platform on the membrane surface, and finally a reaction system of piperazine and trimesoyl chloride (TMC) are used to form a PA NF membrane with a PA active layer. The repairing can construct a coating with a given thickness and prominent hydrophilicity on the membrane surface, which provides favorable base membrane conditions for upgrading and preparing an NF membrane.

Polyamide (PA) nanofiltration (NF) membrane, and preparation method thereof by regeneration from scrapped microfiltration (MF) membrane

A nanofiltration membrane with a high flux for selectively removing hydrophobic endocrine disrupting chemicals and a preparation method thereof are provided. The method includes the following steps: immersing a porous support layer into a first solution, removing excess droplets from a surface of the support layer after taking the support layer out of the first solution, and then immersing the support layer attached with the first solution into a second solution for an interfacial polymerization reaction, followed by washing after completion of the reaction to obtain the subject nanofiltration membrane. The first solution is an aqueous solution containing a polyamine monomer and an acid binding agent, and the second solution is an organic solution containing an acid chloride monomer and a metal-organic framework.

Nanofiltration membrane with high flux for selectively removing hydrophobic endocrine disrupting chemicals and preparation method thereof

A high-performance thin-film composite polyamide membrane upcycled from a substrate fouled with a biopolymer and a preparation method thereof are provided. The method includes fouling the substrate preferably with the biopolymer to obtain a composite of the substrate and a biopolymer foulant layer; then immersing the composite into a first solution formed by dissolving a polyamine monomer in water, followed by taking the composite out of the first solution and removing excess droplets from a surface of the composite; then immersing the composite treated in the previous step into a second solution formed by dissolving an acyl chloride monomer in n-hexane for interfacial polymerization to form a rejection layer on the surface of the composite; and after completion of the reaction, taking the composite out of the second solution, followed by drying and heat treatment, to obtain the target polyamide membrane.

High-performance thin-film composite polyamide membrane upcylcled from biopolymer-fouled substrates and preparation method thereof

A flexible electrocatalytic membrane for removing nitrate from water, a preparation method and use thereof are provided. The method of the present invention includes dropwise adding an aramid fiber solution into deionized water to prepare an aramid nanofiber sol, then reacting an ethanol solution containing 3,4-ethylenedioxythiophene and ferric nitrate with the aramid nanofiber sol to prepare a conductive aramid nanofiber sol, and finally dropwise adding MXene nanosheets ultrasonically pretreated by a tetramethylammonium hydroxide solution into the conductive aramid nanofiber sol to prepare the flexible electrocatalytic membrane. The prepared flexible electrocatalytic membrane possesses good mechanical strength and flexibility, and can not only effectively remove nitrate but also avoid failure of electrocatalytic materials due to surface fouling in the process of electrocatalytic reduction of nitrate, and thus has a long service life.

Flexible electrocatalytic membrane for removing nitrate from water, preparation method and use thereof

A thin-film composite polyamide reverse osmosis membrane with anti-bacterial and anti-biofouling effects and a preparation method thereof are disclosed. The preparation method includes: dissolving a highly water-stable metal organic framework CuBTTri in an n-hexane solution containing trimesoyl chloride by ultrasonic wave, immersing a polyethersulfone ultrafiltration membrane in an aqueous solution of m-phenylene diamine and taking out, and then immersing the ultrafiltration membrane in the trimesoyl chloride-n-hexane solution containing the aforementioned metal organic framework for reaction and modification, so as to obtain the thin-film composite polyamide reverse osmosis membrane. The resulting composite reverse osmosis membrane integrated with the anti-bacterial metal organic framework CuBTTri has a high reverse osmosis membrane permeability and possesses greatly improved and persistent anti-bacterial and anti-biofouling properties. The preparation method is simple and conducive to promotion, and has mild conditions.

Thin-film composite polyamide reverse osmosis membrane with anti-bacterial and anti-biofouling effects and preparation method thereof

An electrochemical membrane module for selectively removing pollutants and a preparation method thereof are provided. A Ti/SnO&#x2014;Sb substrate electrode is coated with a MI&#x2014;TiOsol-gel by means of a dip-coating method, and then sintered to obtain a molecular imprinting type Ti/MI&#x2014;TiO/SnO&#x2014;Sb coated electrode; the coated electrode is adhered to a ceramic micro-filtration membrane using epoxy resin glue to obtain a Ti/MI&#x2014;TiO/SnO&#x2014;Sb MI-anodic conductive composite membrane; the MI-anodic conductive composite membrane is used as an anode, and a titanium mesh is used as a cathode, so that the electrochemical membrane module capable of selectively removing pollutants is obtained. The invention effectively combines an electrochemical micro-filtration membrane and a molecular imprinting technique. When the electrochemical membrane module is used, suspended particles and refractory organics in the sewage are removed, and a highly selective removal of certain refractory pollutants can be achieved.

Electrochemical membrane module for selectively removing pollutants and preparation method thereof

To provide a modified forward osmosis (FO) membrane module for flow regime improvement, the FO membrane module includes but not limited to: a water inlet; a water outlet; a forward osmosis (FO) membrane; a frame; and folded plates for improving flow regime in which draw solution is introduced into the water inlet of membrane module, then flowed through flow channels composed by three opposite folded plates vertically arranged on upper and bottom portions of the frame alternatively along horizontal direction with equal space; and drawn out from the water outlet. The flow regime improvement is achieved by increasing number of flow-guide folded plate, which results in the decrease of internal concentration polarization and membrane fouling. Structure of frame is modified to improve flow regime and to satisfy requirement of convenient and reliable connections between numbers of membrane modules in the FO membrane system.

Modified forward osmosis membrane module for flow regime improvement

This invention provides a polymeric separation membrane that has excellent durable antibacterial effect and stain resistance, and a preparation method thereof. The polymeric separation membrane can be widely applied for water treatment, which belongs to the field of water treatment and membrane separation science and technology. The polymeric separation membrane containing quaternary ammonium salt is prepared by the immersion precipitation phase inversion method, using quaternary ammonium salt mixed with polymer and additives. This modification method effectively improves the antibacterial and antifouling ability of the polymeric separation membrane prolongs the service life of membranes and significantly inhibits the reproduction of bacterial and microbial. The preparation method has the advantages of simple process, easy operation, easy for promotion, and also avoids expensive equipment. The polymeric separation membrane has great antibacterial ability and stain resistance, therefore, it has potential application in the field of water treatment.

Antibacterial and antifouling polymeric separation membrane and preparation method thereof

The present invention provides a method of fabricating a 3D stacked IC SiP which includes: providing a first semiconductor wafer having a plurality of first dies formed thereon, each having a first wire bond pad and a first dielectric layer, at least a portion of the first wire bond pad is not covered by the first dielectric layer and constitutes an exposed area of the first die; providing a plurality of second dies, each having a second wire bond pad and a second dielectric layer, at least a portion of the second wire bond pad is not covered by the second dielectric layer and constitutes an exposed area of the second die different in size from that of the first die; aligning the second dies with the first dies and bonding the second dielectric layer to the first dielectric layer; plating the first semiconductor wafer bonded with the second dies.

Methods of fabrication and testing of three-dimensional stacked integrated circuit system-in-package

The present invention relates to a pressure sensor, which may include a first electrode plate, a second electrode plate, a third electrode plate, a fourth electrode plate and a fifth electrode plate, which are successively laminated on a substrate, wherein the first electrode plate, the third electrode plate and the fourth electrode plate are fixed to the substrate, the first electrode plate and the second electrode plate are disposed opposite to each other and have a gap formed therebetween, the second electrode plate is suspended over the first electrode plate to constitute a first capacitor; the second electrode plate and the third electrode plate are disposed opposite to each other and have a gap formed therebetween, to constitute a second capacitor; and the fifth electrode plate is suspended over the fourth electrode plate to constitute a third capacitor, and can move along a direction perpendicular to the substrate.

Growing community of inventors

Shanghai, China

Zhiwei Wang