Sennics Co., Ltd.

Zhimin Tang

Xiangyun Guo

Jinguo Xing

Yang Gao

Hui Li

Yan Li

Qi Qi

Haibo Zhu

Gan Liang

Jiaqiang Zhang

Yanxiang Liu

A compound having anti-aging and discoloration resistance effects and a preparation method therefor are provided. The structure of the compound is represented by formula (I). The compound provides longer-lasting anti-aging performance, and has discoloration resistance. The compound may be used as an anti-aging agent in rubber products, especially rubber tires, and can prevent the aging and deterioration of rubber products or rubber tires due to light, heat, oxygen, and fatigue, during use.

Compound having anti-aging and discoloration resistance effects and preparation method therefor

A polyalkyl p-phenylenediamine antidegradant having a structure represented by Formula I, its intermediates and a preparation method thereof are provided. The polyalkyl p-phenylenediamine antidegradant provides good thermal oxidative aging resistance and UV aging resistance.

Polyalkyl p-phenylenediamine anti-degradants and intermediates and preparation method thereof

A method for preparing a diaryl-p-phenylenediamine compound of Formula I comprises the steps of reacting a compound of Formula II and a compound of Formula III in a condensation dehydrogenation reaction in the presence of a solvent, a hydrogen acceptor, a water-carrying agent, and a catalyst; wherein R, Rand Rare independently selected and each is H, a C1-C8 alkyl, a C3-C8 cycloalkyl, a C1-C8 alkoxy, a C3-C8 cycloalkoxy, or phenyl; a and c are independently selected and each is an integer of 0 to 5, and b is an integer of 0 to 4:

Method for preparing diaryl p-phenylenediamine compounds

A formulation for rubber composition with reduced odor and good thermal oxidative aging-resistance and tension fatigue resistance comprising 100 parts by weight of a diene elastomer, 30 to 70 parts by weight of a reinforcing filler, 0.1 to 8 parts by weight of an antidegradant composition, and 0.5 to 3 parts by weight of a crosslinker, wherein the antidegradant composition includes a 6PPD antidegradant with a purity of equal to or greater than about 98% and an S-TMQ. The rubber composition has no added odor inhibitor/adsorbent or deodorizing additive, while by using combination of 6PPD with purity of equal to or greater than about 98% and an S-TMQ instead of traditional combination of 6PPD and a TMQ, the VOC emission of the rubber composition is effectively reduced, the odor grade is reduced, and the thermal oxidative aging-resistance and tension fatigue resistance is improved.

Rubber composition with reduced odor and good thermal oxidative aging-resistant and anti-fatigue properties

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Shanghai, China

Zhimin Tang