China University of Petroleum

Qingdao University

Zhaojun Chen

Hui Du

Jun Li

Jianguo Zhang

Dong Liu

Changlong Yin

Zhihao Li

Xiujie Yang

Xin Gong

Fushan Wen

Nan Shi

Bin Lou

Zhiqing Ma

Chong Jiao

Yonggang Cao

Hui Fu

Luning Chai

Jinzhe Fu

Yajing Duan

Zhichen Zhang

Enqiang Yu

Yu'e Fu

Huizhi Yuan

A molybdenum disulfide/graphene/carbon composite material having a hierarchical pore structure includes a composite nanofiber having a diameter of 60 to 500 nm. The composite nanofiber comprises, in mass percentage, 3% to 35% of molybdenum disulfide, 0.2% to 10% of graphene, and 60% to 95% of carbon. The composite nanofiber has a hierarchical pore structure distributed along the axial direction, and has a pore diameter continuously distributed between 0.1 nm and 5 μm and an average pore diameter between 1.5 nm and 25 nm. On the basis of the pore volume, in the hierarchical pore structure, a micropore structure accounts for 25% to 60%, and a mesoporous structure accounts for 40% to 75%. The microporous structure is distributed on the surface of the nanofiber and the pore wall of the mesoporous structure.

Molybdenum disulfide/graphene/carbon composite material and use thereof

Preparation methods of a high modulus carbon fiber (HMCF) and a precursor (mesophase pitch (MP)) thereof are provided. The preparation method of MP includes: separating components with a molecular weight distribution (MWD) of 400 to 1,000 from a heavy oil raw material through size-exclusion chromatography (SEC); subjecting the components to ion-exchange chromatography (IEC) to obtain modified feedstock oil, where, the components are passed through macroporous cation-exchange and anion-exchange resins in sequence to remove acidic and alkaline components; and subjecting the modified feedstock oil to thermal polycondensation and carbonization to obtain high-quality MP with prominent spinnability. With high mesophase content, low softening point, low viscosity, and prominent meltability and spinnability, the obtained MP is a high-quality raw material for preparing HMCFs. The obtained MP can be subjected to melt spinning, pre-oxidation, carbonization, and graphitization to obtain an MP-based HMCF.

Preparation methods of high modulus carbon fiber (HMCF) and precursor (mesophase pitch (MP)) thereof

Growing community of inventors

Qingdao, China

Zhaojun Chen