Shenzhen Capchem Technology Co., Ltd.

Zhaohui Deng

Hao Zhang

Hui Li

Qiao Shi

Shiguang Hu

Muchong Lin

Xionggui Lin

Zhongtian Zheng

Ling Zhong

Changchun Chen

Chunhua Liu

In order to solve the problems of insufficient high-temperature storage performance and high-temperature cycle performance of the existing lithium ion battery, the present application provides a non-aqueous electrolyte for lithium ion battery, comprising a bicyclic sulfate compound and a compound A represented by structural formula 1. In structural formula 1, R, R, R, R, Rand Rare each independently selected from hydrogen, fluorine atom or a group containing 1˜5 carbon atoms. Meanwhile, the application also discloses a lithium ion battery comprising the non-aqueous electrolyte for lithium ion battery. The non-aqueous electrolyte for lithium ion battery provided by the application is beneficial to improving high-temperature storage and high-temperature cycle performance of battery.

Non-aqueous electrolyte for lithium ion battery and lithium ion battery

To solve the problems that the existing non-aqueous electrolyte for lithium ion battery containing fluorinated solvent generates serious gas expansion when improving high-temperature cycle performance and affects high-temperature safety performance of battery. The application provides a non-aqueous electrolyte for lithium ion battery. The non-aqueous electrolyte for lithium ion battery comprises a compound A and a compound B, wherein the compound A is at least one of compounds represented by the following structural formula I, formula II and formula III; the compound B is a compound represented by the following structural formula IV; formula I: R&#x2014;COO&#x2014;R; formula II: R&#x2014;OCOO&#x2014;R. The non-aqueous electrolyte for lithium ion battery provided by the invention contains both the compound A and the compound B, the synergistic effect of compound A and compound B can effectively improve high-temperature cycle performance and high-temperature storage performance of battery, and can also give consideration to low-temperature performance of battery. 

Provided is a non-aqueous electrolyte for lithium ion battery, comprising a compound A represented by structural formula I and a compound B represented by structural formula II: Wherein, in formula I, Ris selected from alkylene having 1-5 carbon atoms or fluorine substituted alkylene having 1-5 carbon atoms; Ris selected from anyone of alkylene having 1-5 carbon atoms, fluorine substituted alkylene having 1-5 carbon atoms or carbonyl; In formula II, R, R, R, R, Rand Rare each independently selected from hydrogen, fluorine atom or a group containing 1-5 carbon atoms. The compound A and compound B of the non-aqueous electrolyte can form a passivation film formed by reduction, decomposition and combination reactions on the surface of negative electrode material of lithium-ion battery, thereby improving thermal stability of the passivation film and high-temperature cycle and storage performance of the battery.

Provide is a non-aqueous electrolyte for lithium ion battery, comprising a compound represented by structural formula I:  In formula I, R, R, Rand Rare each independently selected from hydrogen atom, fluorine atom, cyano group, hydrocarbyl group or halogenated hydrocarbyl group having 1-5 carbon atoms, oxygen-containing hydrocarbyl group having 1-5 carbon atoms, silicon-containing hydrocarbyl group having 1-5 carbon atoms, X is a &#x2014;O&#x2014;R&#x2014;CN group, Ris a hydrocarbyl group or a halogenated hydrocarbyl group having 1-5 carbon atoms, m, n, z and y are integers of 0 or 1, and m+n+y+z&#x2260;0. When the non-aqueous electrolyte is used for lithium ion battery, the decomposition of electrolyte on the surface of electrode can be inhibited, and the high-temperature storage performance is improved with less gas generation and small expansion rate, therefore the high-temperature cycle performance and high-temperature storage performance of the battery are effectively improved.

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Guangdong, China

Zhaohui Deng