Southwest Petroleum University

Tianfu Yongxing Laboratory

Zezhou Fang

Jinzhou Zhao

Wanfen Pu

Daijun Du

Rui Liu

Fayang Jin

Bo Zhou

Zijia Liao

Chao Shen

Ying Xiong

Jintao Li

Rui Jiang

Peiwen Xiao

Yangyang Zhang

The present invention discloses a supercritical CO2 thickener for shale gas reservoir based on hollow mesoporous silica nanoparticles and a preparation method thereof, and relates to the technical field of oil and gas field development. The preparation method of the thickener includes: reacting a monomer consisting of fluoroacrylate, styrene and vinyl acetate in a molar ratio of 3-5:1-2:1-2 with 2%-5% of a total weight of hollow mesoporous silica nanoparticles with carbon-carbon double bonds under the action of an initiator to obtain the thickener. The preparation method of the present invention does not involve the addition of organic solvents during the reaction process and thus does not cause harm to the human body. The thickener of the present invention has good CO2 viscosity-increasing effect and good sand carrying performance, and can effectively improve the fracturing effect.

Supercritical CO2 thickener for shale gas reservoir based on hollow mesoporous silica nanoparticles and preparation method thereof

The present invention discloses a CO2 responsive core-shell multi-stage swelling microsphere and a preparation method thereof. The preparation method comprises the following steps: adding a styrene monomer into a sodium dodecyl sulfate solution for emulsion polymerization to obtain a spherical polystyrene solution, taking azobisisobutyronitrile and ethylene glycol for Pinner reaction to obtain an azo compound with hydroxyl functional groups at two ends, taking the azo compound with the hydroxyl functional groups at two ends as a raw material for Schotten-Baumann reaction with methacryloyl chloride to obtain BPAB, adding the BPAB into the spherical polystyrene solution to prepare an active polystyrene core solution, and dissolving the active polystyrene core solution, acrylamide, a CO2 responsive monomer, a CO2 responsive cross-linking agent and a stable cross-linking agent into water to obtain a target product. The CO2 responsive core-shell multi-stage swelling microsphere of the present invention can remarkably improve the CO2 flooding sweep efficiency.

CO2 responsive core-shell multi-stage swelling microsphere and preparation method thereof

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Chengdu, China

Zezhou Fang