Saudi Arabian Oil Company

Zaki Yusuf

Ahmad D Hammad

Bandar A Fadhel

Stamatios Souentie

Nayif A Rasheedi

Alberto Lozano Ballesteros

Abdul Rahman Zafer Akhras

Ali Hoteit

Konstantinos Kotsovos

Atef Al-Zahrani

Per Tobias Mattisson

Amjaad Al-Qahtani

Nayif A Al-Rasheedi

Atef Saeed Al-zahrani

Ali Hoteit Abqaiq

Ahmad D Haamad

Nayif Rasheedi

Methods of extracting 1-4 cycle heterocyclic compounds and 2-5 cycle polynuclear aromatic hydrocarbons from a hydrocarbon feedstock are described. The methods include providing a hydrocarbon feedstock containing crude oil fractions, and determining an A/R ratio and an asphaltene concentration of the hydrocarbon feedstock. Based upon the A/R ratio and the asphaltene concentration, the treatable hydrocarbon feedstock undergoes one or more of cracking and fractionating. Subsequently, at least one targeted portion of the heterocyclic compounds is extracted from the fractionated stream with an aqueous solvent. A stream containing the 2-5 cycle polynuclear aromatic hydrocarbons is transferred to an extractor and the 2-5 cycle polynuclear aromatic hydrocarbons are extracted with a solvent system comprising an aprotic solvent.

Systems and methods for separation and extraction of heterocyclic compounds and polynuclear aromatic hydrocarbons from a hydrocarbon feedstock

A process for producing black powder oxygen carriers for use in a chemical looping combustion unit includes the steps of: (a) removing and collecting the black powder waste material that was formed in a gas pipeline; (b) pre-treating the collected black powder to adjust its spherical shape to avoid attrition and fines production; and (c) activating the black powder to increase its reactivity rate and produce the black powder oxygen carrier that is suitable for use in the chemical looping combustion process as an oxygen carrier.

Activation of waste metal oxide as an oxygen carrier for chemical looping combustion applications

A photocatalytic power generation system including a solar housing, a photoanode, an electrolyte membrane, a cathode, an oxygen diffusion membrane, and an external power generation circuit. The photoanode and the cathode are each positioned within the solar housing and electrically coupled to the external power generation circuit. The electrolyte membrane is positioned between and electrochemically engaged with the photoanode and the cathode forming a photocatalytic cell. The solar housing comprises a closed-loop water chamber having an anode side flow channel, a cathode side flow channel, a recombined water channel, and an oxygen diffusion membrane. Further, the oxygen diffusion membrane is positioned and configured to inhibit recombined water generated at the cathode from flowing from the cathode side to the anode side along the oxygen transport channel and permit recombined water generated at the cathode from flowing from the cathode side to the anode side along the recombined water channel.

System and method for power generation with a closed-loop photocatalytic solar device

A solar system is provided comprising a light receiving surface, a condensation subassembly, a water collection subassembly, and a cleaning subassembly. The expansion chamber of the condensation subassembly is thermally coupled to the light receiving surface and thermally insulated from the ambient such that expansion of compressed air in the expansion chamber, as controlled by the compressed air expansion valve, encourages humidity condensation on the light receiving surface by reducing the temperature of the light receiving surface. The water collection subassembly comprises a water collection vessel and water direction hardware positioned to direct condensed water on the light receiving surface to the water collection vessel. The cleaning subassembly comprises a water dispensing unit positioned to dispense water from the water collection vessel over the light receiving surface of the solar system.

Solar system comprising self sustainable condensation, water collection, and cleaning subassemblies

A process and system for improving the efficiency of regenerating a CO-rich liquid absorbent stream following contact in an absorption zone with, e.g., a flue gas stream from which it has absorbed CO, and recovering a substantially pure stream of includes passing the pressurized liquid sorbent through a heating zone to heat it to the desorption temperature, e.g., to about 80&#xb0;-85&#xb0; C. for aqueous KCOsorbent, introducing the heated liquid sorbent into a cyclone separation zone where the combination of increased temperature, reduced pressure and the centrifugal forces on the liquid/gas mixture result in a relatively more rapid and efficient separation of the COfrom the liquid sorbent from which it has been released. The CO-lean liquid sorbent descends to the bottom of the cyclone separator and is recovered, cooled and recycled to the absorption zone; the COwithdrawn from the cyclone separation zone passes through a condenser to remove moisture and any other condensates present, and the COis recovered for storage or use in downstream processes.

Cyclone separation and recovery of carbon dioxide from heated liquid absorbent

Methods are provided for extracting heterocyclic compounds, organometallic compounds, and polynuclear aromatic hydrocarbons from a hydrocarbon feedstock such as crude oil or a crude fraction. The heterocyclic compounds and organometallic compounds are removed from the hydrocarbon feedstock through one or more successive extractions to form a first raffinate. The extractions use a first solvent system containing an ionic liquid formed from carbon dioxide and water. The polynuclear aromatic hydrocarbons are removed from the first raffinate using a second solvent system containing an aprotic solvent such as NMP, DMSO, aromatics, or combinations thereof. The extracted compounds remain chemically intact and may be fractionated for further applications. Further methods are provided for producing a hydrocarbon raffinate having reduced levels of heterocyclic compounds, organometallic compounds, and 2-4 cycle polynuclear aromatic hydrocarbons.

Integrated methods for separation and extraction of polynuclear aromatic hydrocarbons, heterocyclic compounds, and organometallic compounds from hydrocarbon feedstocks

The invention relates to methods for making completely biodegradable, hydrophobic, oleophilic plant based materials which are useful in adsorption of petroleum products. The materials have an average diameter of from 1 to 5 mm, and an ash content of from 10% to 30%. The non-paraffin coating is an animal fat product, preferably produced by dissolving a pure animal fat and using this as the coating material.

Process for preparing lipid coated particles of plant material

A demulsification process for extracting surface active biochemical products from crude oil and its fractions when they are used as feedstock during biochemical productions utilizes subcritical/supercritical COas a proton pump. The process also includes a pH tuning step, thereby inducing demulsification and precipitation of biochemical products into the aqueous phase, but avoiding asphaltene precipitation by apriori addition of resinous solvents derived from crude oil or bioresources. The biochemical products are then extracted from the aqueous phase via temperature change or some other technique.

Demulsification and extraction of biochemicals from crude and its fractions using water and subcritical/supercritical carbon dioxide as proton pump with pH tuning without precipitating oil components

Methods for recovering organic heteroatom compounds from a hydrocarbon feedstock include feeding into a contactor a hydrocarbon feedstock and an aqueous solvent to form an extraction mixture of the aqueous solvent with the hydrocarbon feedstock. The hydrocarbon feedstock includes a hydrocarbon and an organic heteroatom compound. The aqueous solvent includes an ionic liquid formed from pressurized carbon dioxide and water. A pressure and temperature of the extraction mixture may be established that together tune the aqueous solvent to selectively form a solvent complex with the at least one organic heteroatom compound. Then, the solvent complex is extracted to a recovery vessel from the extraction mixture in the contactor. By adjustment of a recovery temperature of the recovery vessel, a recovery pressure of the recovery vessel, or both, the solvent complex decomposes into carbon dioxide and the organic heteroatom compound. The organic heteroatom compound is then recovered from the recovery vessel.

Methods for recovering organic heteroatom compounds from hydrocarbon feedstocks

A process for converting carbon dioxide to hydrocarbon fuels using solar energy harnessed with a solar thermal power system to create thermal energy and electricity, using the thermal energy to heat a fuel feed stream, the heated fuel feed stream comprising carbon dioxide and water, the carbon dioxide captured from a flue gas stream, converting the carbon dioxide and water in a syngas production cell, the syngas production cell comprising a solid oxide electrolyte, to create carbon monoxide and hydrogen, and converting the carbon monoxide and hydrogen to hydrocarbon fuels in a catalytic reactor. In at least one embodiment, the syngas production cell is a solid oxide fuel cell. In at least one embodiment, the syngas production cell is a solid oxide electrolyzer cell.

Carbon dioxide conversion to hydrocarbon fuel via syngas production cell harnessed from solar radiation

Methods for demulsifying an emulsified petroleum source having a predetermined resin-to-asphaltene ratio without substantial aggregation or precipitation of asphaltenes may include adding a resin supplement to the emulsified petroleum source to form a resin-supplemented emulsion having a resin-to-asphaltene ratio above a predetermined critical value. An acidic-to-basic ratio of acidic functional groups to basic functional groups in the supplemented emulsion may be adjusted to be from about 0.25 to about 4.0. The resin-supplemented emulsion may be contacted with carbon dioxide to form an initial mixture having an emulsified oil phase and an emulsified aqueous phase. The initial mixture may be stabilized to facilitate rupture of the resin-supplemented emulsion, to cause phase separation, and to allow removal of a separated oil phase. The resin-to-asphaltene ratio being above the predetermined critical value in the supplemented emulsion maintains asphaltene suspension during demulsification, such that asphaltene agglomeration and precipitation are avoided.

Demulsification of emulsified petroleum using carbon dioxide and resin supplement without precipitation of asphaltenes

The invention relates to a method for removing oxygen from a water containing reaction medium. A pair of electrodes (cathode and anode), are added to the medium, with a surfactant attached to the surface of at least one of the cathode and anode. The medium is kept at an acidic pH, and an electrical current is applied. Oxygen is drawn to the electrodes, displacing surfactant, and reacts with Hions and HO molecules to form HO, which can then be removed.

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Dhahran, Saudi Arabia

Zaki Yusuf