Hrl Laboratories, LLC

The Boeing Company

Zak C Eckel

Jacob Michael Hundley

Sophia Shu Yang

Alan Jon Jacobsen

Tobias A Schaedler

Eric C Clough

William B Carter

Christopher Stephen Roper

April Rose Rodriguez

Phuong Bui

Andrew Paul Nowak

John Hunter Martin

Kenneth Cante

Scott Biesboer

Ashley M Dustin

David Page

Jie Jiang

Thomas I Boundy

Chaoyin Zhou

Adam E Sorensen

Mark O'Masta

Robert Mone

Tony Koung

Christopher J Ro

Jie Ensberg

Geoffrey P McKnight

Blaine Knight Rawdon

Florian G Herrault

Eddie Kwon

Darrin Michael Hansen

Jason Scott Damazo

Sloan Patrick Smith

John Rubrecht Lowell

Randall C Schubert

Joanna A Kolodziejska

Matthew Howard Cawthorne

Ashley M Nelson

Darby Laplant

Julie Miller

Michael Scott Cameron

Kevin J Maloney

Jacob John Mikulsky

Edward W Brouwers

Kayleigh A Porter

Geoffrey P Mcknight

Alvin Escobar

Emily C Schueller

Scott M Biesboer

Phuong P P Bui

Joanna Kolodziejska

Jenny Jiang

This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.

Formulations with active functional additives for 3D printing of preceramic polymers, and methods of 3D-printing the formulations

This disclosure provides resin formulations which may be used for 3D printing and thermally treating to produce a ceramic material. The disclosure provides direct, free-form 3D printing of a preceramic polymer, followed by converting the preceramic polymer to a 3D-printed ceramic composite with potentially complex 3D shapes. A wide variety of chemical compositions is disclosed, and several experimental examples are included to demonstrate reduction to practice. For example, preceramic resin formulations may contain a carbosilane in which there is at least one functional group selected from vinyl, allyl, ethynyl, unsubstituted or substituted alkyl, ester group, amine, hydroxyl, vinyl ether, vinyl ester, glycidyl, glycidyl ether, vinyl glycidyl ether, vinyl amide, vinyl triazine, vinyl isocyanurate, acrylate, methacrylate, alkacrylate, alkyl alkacrylate, phenyl, halide, thiol, cyano, cyanate, or thiocyanate. The resin formulations may contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material.

Preceramic 3D-printing monomer and polymer formulations

A method of repairing a sandwich structure includes: removing a damaged portion of a core and a damaged portion of a first facesheet to form an open volume; filling the open volume with an ultraviolet-curable photomonomer; partially curing the ultraviolet-curable photomonomer to form a plurality of photopolymer waveguides by utilizing ultraviolet light; and arranging a replacement facesheet on the damaged portion of the first facesheet and over the photopolymer waveguides.

Method of repairing sandwich structure

Some variations provide a composition for additive manufacturing (3D printing) of metals, comprising: from 10 vol % to 70 vol % of a photocurable liquid resin; from 10 vol % to 70 vol % of metal or metal alloy particles, optionally configured with a photoreflective surface; and from 0.01 vol % to 10 vol % of a photoinitiator. Other variations provide a composition for additive manufacturing of metals, comprising: from 1 vol % to 70 vol % of a photocurable liquid resin; from 0.1 vol % to 98 vol % of an organometallic compound containing a first metal; from 1 vol % to 70 vol % of metal or metal alloy particles containing a second metal (which may be the same as or different than the first metal); and from 0.01 vol % to 10 vol % of a photoinitiator. Many examples of metals, photocurable resins, organometallic compounds, photoinitiators, and optional additives are disclosed, and methods of making and using the composition are described.

Resin formulations for additive manufacturing of metals, and methods of making and using the same

Monomer formulations and methods for 3D printing of preceramic polymers

The present disclosure provides a methodology in which nanoparticle-coated microparticles are rapidly quality-checked for verification of surface functionalization of a commercial quantities of hierarchical powder. Some variations provide a method for inspecting surface-functionalized microparticles, comprising: selecting samples of hierarchical powders comprising microparticles and surface-coated nanoparticles; subjecting the hierarchical powders to a sample particle-size measurement; comparing the sample particle-size measurement to a baseline measurement; and determining the relative concentration of free nanoparticles, based on particle-size distributions. If the sample particle-size measurement is statistically equivalent to the baseline measurement, that is verification of complete surface functionalization. If the sample particle-size measurement is statistically different than the baseline measurement, then the baseline measurement is subtracted from the sample particle-size measurement, to determine the content of free nanoparticles. Optionally, the surface-coated nanoparticles are removed from the sample and additional particle-size distributions measured, to determine the content of original surface-coated nanoparticles, for additional quality control.

Methods and systems for inspecting hierarchical powders and verifying the functionalization of powder surfaces

A method of manufacturing a sandwich structure having an open cellular core and a fluid-tight seal surrounding the core includes coupling a mold to a first facesheet to define a reservoir. The method also includes irradiating a volume of photo-monomer in the reservoir with a series of vertical collimated light beams to form a cured, solid polymer border extending around a periphery of the first facesheet. The method also includes irradiating a remaining volume of photo-monomer in the reservoir with a series of collimated light beams to form an ordered three-dimensional polymer microstructure core defined by a plurality of interconnected polymer optical waveguides coupled to the first facesheet and surrounded by the cured, solid polymer border. The method further includes coupling a second facesheet to the ordered three-dimensional microstructure core and the cured, solid polymer border to form the sandwich structure.

Open cellular sandwich structures having sealed edges and methods of manufacturing the same

A fire retardant (FR) composite composition, including a liquid polymer, wherein the liquid polymer includes a photopolymer including at least two of a first molecule, a second molecule, and a third molecule, a FR thermoset, and a photoinitiator.

FR composite composition for light-based additive manufacturing

A system for fabricating composite parts efficiently. Pre-impregnated (prepreg) composite material is drawn as a sheet from a roll and fed by advancement rollers into a stamping and molding station in which a piece of the prepreg material is cut, on a mold, from the sheet. Pressure is applied to cause the prepreg material to conform to a surface of the mold, and the prepreg is cured with ultraviolet light. Additional layers of prepreg may be cut and cured on any layers that have already been cured on the mold. The complete part may be removed from the mold with ejector pins. Scrap prepreg may be recycled in a recycling station that separates reinforcing fiber from uncured resin.

Device for in-line consolidation of composite materials

A composition for forming a microlattice structure includes a photopolymerizable compound and a flame retardant material. A microlattice structure includes a plurality of struts interconnected at a plurality of nodes, the struts including: a copolymer including a reaction product of a photopolymerizable compound and a flame retardant material. A microlattice structure includes a plurality of struts interconnected at a plurality of nodes, the struts including: a polymer including a reaction product of a photopolymerizable compound; and a flame retardant material.

Microlattice structures including flame retardant materials and compositions and methods for forming the same

Method of repairing sandwich structure and repaired sandwich structure

A method and a fugitive mold for producing a cast-metal part are provided. In some embodiments, the fugitive mold may be formed by three-dimensionally (3D) printing a preceramic resin in the shape of a fugitive mold; curing the preceramic resin to form a preceramic polymer, and pyrolyzing the fugitive mold to convert the preceramic polymer to a metastable ceramic material. The metastable ceramic material may include an amorphous silicon oxycarbide ceramic. A cast-metal part may be formed by filling the fugitive mold with a liquid metal or alloy, and allowing the liquid metal or alloy to solidify over a first length of time. The cast-metal part may then be retrieved by heating the fugitive mold at a temperature lower than the melting point of the cast-metal part for a second length of time longer than the first length of time to disintegrate the metastable ceramic material.

Fugitive ceramic mold, formulations and method for investment casting

A system for forming a structural member which includes a first collimated light source and a reservoir containing a volume of photo-monomer resin wherein the first collimated light source is positioned spaced apart from the photo-monomer resin. The system further includes a first face sheet structure defining at least one bore which extends through the first face sheet structure wherein a portion of the first face sheet structure is positioned under a surface of the volume of photo-monomer resin such that photo-monomer resin is positioned within the bore.

System and method for making pin reinforced sandwich panel and resulting panel structure

A sandwich structure configured to be secured with a mechanical fastener includes a core assembly, which includes a polymer component configured for supporting a mechanical fastener connector insert. The core assembly further includes an open cellular component formed from a plurality of self-propagating photopolymer waveguides positioned around the polymer component, wherein a first portion of the plurality of self-propagating photopolymer waveguides is secured to and extends from the polymer component. Further included is a first face sheet secured to a first side of the core assembly, wherein the first portion of the plurality of self-propagating photopolymer waveguides has a distal end spaced apart from the polymer component and secured to the second face sheet.

Integrated fastener insert for open cellular sandwich structure and method to install

Growing community of inventors

Calabasas, CA, United States of America

Zak C Eckel