Lumas Polymers LLC

Jabil Inc.

Zachary Peterson

Thomas Fry

Mathew Artin Torosian

Steven Kubiak

Nicholas J Dippel

Levi Loesch

Luke Rodgers

John Gordon Eue

Nicholas John Dippel

Matthew A Torosian

An end capped condensation polymer may be formed by heating a condensation polymer in the presence of an end capping compound to form cleaved condensation polymer reacting at least a portion of the cleaved condensation polymer with the end capping compound to form the end capped condensation polymer. The end capped condensation polymers may be used to form additive manufactured articles having high solids loading and improved processing due to improved rheological behavior.

Chain scission to make improved polymers for 3D printing

A bullet (ammunition projectile) comprising a branched condensation polymer and a filler, wherein the filler is present in an amount from about 10% to 65% by volume of the branched condensation polymer and filler is described. The bullet may be made by heating a mixture comprised of a branched condensation polymer and a filler comprised of a first and second filler having differing densities and differing particle size distribution to form a molten mixture and injecting the molten mixture into a mold to form the ammunition projectile allowing for the tailoring of the characteristics of the bullet for differing applications.

Lead-free ammunition projectile

In one instance a semicrystalline polyketone powder useful for additive manufacturing is comprised of a bimodal melt peak determined by an initial differential scanning calorimetry (DSC) scan at 20° C./min and a Dparticle size of at most 300 micrometers and average particle size of 1 micrometer to 150 micrometers equivalent spherical diameter. In another instance, A composition is comprised of a semicrystalline polyketone powder having a melt peak and a recrystallization peak, wherein the melt peak and recrystallization peak fail to overlap.

Polyketone powder for laser sintering

An additive manufactured condensation polymer article with improved build or Z direction strength may be formed by physically mixing or depositing thereon a chain extender that extends and chemically bonds the polymer chains within and between layers upon heating and fusing during the additive manufacturing process.

Method for improving adhesion in and between layers of additive manufactured articles

A semicrystalline poly ketone powder useful for additive manufacturing may be made by dissolving a polyketone having differential scanning calorimetry (DSC) monomodal melt peak, at a temperature above 50° C. to below the melt temperature of the polyketone, precipitating the dissolved polyketone by cooling, addition of a nonsolvent or combination thereof. The method may be used to form polyketones having a DSC melt peak with an enthalpy greater than the starting polyketone.

A composition useful for additive manufacturing is comprised of a thermoplastic elastomer blended with an aliphatic polyketone, wherein the thermoplastic elastomer is a continuous phase having dispersed therein separated domains of polyketone. The composition is useful for additive printing methods employing heating and extrusion of the composition to form extrudates that are printed an article comprised of fused layers of the composition. The composition facilitates the formation of extrusion based elastomeric additive manufactured articles.

Elastomeric additive manufacturing composition

Useful thermoplastic polymer powders are formed by a method comprising: cooling a foam comprised of a thermoplastic foam below the brittleness temperature of the thermoplastic polymer, wherein the foam has an average strut dimension of 10 to 500 micrometers, and comminuting the cooled foam to form a thermoplastic polymer powder. The method allows for the efficient grinding of the thermoplastic polymer having improved morphology and desirable characteristics such as dry flow without flow aids.

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New Hope, MN, United States of America

Zachary Peterson