Lawrence Livermore National Security, LLC

Current Lighting Solutions, LLC

General Electric Company

Gatan, Inc.

Zachary M Seeley

Nerine Jane Cherepy

Stephen Anthony Payne

Alok Mani Srivastava

Joshua D Kuntz

Eric B Duoss

William Winder Beers

Thomas Frederick Soules

William Erwin Cohen

Cheng Zhu

Joel P Hollingsworth

Ross Allen Osborne

Ivy Krystal Jones

Mark S Andreaco

Matthias J Schmand

Peter Carl Cohen

Edward Michael James

Colin Trevor

David Joyce

Joseph Webster

Steven A Payne

Colin Geoffrey Trevor

The present disclosure relates to a lighting component which may comprise a light emitting diode (LED) or laser diode (LD) for generating at least one of blue light or ultraviolet light. A fluoride phosphor matrix may be included, which may be consolidated into a phosphor ceramic structure including at least one of a transparent fluoride ceramic structure or a translucent fluoride ceramic structure, and positioned adjacent to the LED or LD. The phosphor ceramic structure generates at least one of red or orange light when irradiated by the light emitted from the LED or LD. The phosphor ceramic structure exhibits reduced thermal quenching relative to a fluoride particulate structure irradiated by the LED or LD.

Systems and methods for fluoride ceramic phosphors for LED lighting

In one aspect, a composition of matter includes: a plurality of particles in a thixotropic suspension to form an ink, where the plurality of particles are present in an amount of at least about 20 vol %, and the plurality of particles include: a first host medium material containing at least one of: one or more lasing species dopants; and one or more other dopant species; and a second host medium material containing at least one other dopant species. The composition of matter further includes a liquid phase present in an amount greater than 20 vol % and less than about 80 vol %, where the liquid phase comprises at least one of: at least one surfactant; at least one polar organic solvent; and at least one binder.

Laser gain media fabricated via direct ink writing (DIW) and ceramic processing

A transparent ceramic optic includes: a lasing region comprising at least one lasing species dopant; and a transparent region transparent to light generated by the lasing species. At least the transparent region is doped with at least one other dopant species such that the lasing region and the transparent region are characterized by a difference in refractive index between the two regions in an amount of about 1.0&#xd7;10or less. Inventive formulations of inks suitable for fabricating transparent ceramic optics having desirable compositional characteristics such as concentration gradients in desired spatial arrangements, e.g. using additive manufacturing techniques such as direct ink writing and/or extrusion freeform fabrication are also disclosed, along with suitable techniques for forming the transparent ceramic optics from such inks.

A fast-decaying, dense phosphor having relatively high light emission is described. Through a combination of material selection, growth and deposition technique, phosphor thin films are made that preserve the necessary light output when used in thin-films, unlike common fast phosphors, such as P-46, P-47, and also have an afterglow that decays much faster than common bright phosphors, such as P-43. Use of the phosphor is described in applications where acquiring many frames/images very quickly is required.

High density fast phosphor for electron microscopy

In one embodiment, a method includes forming a powder having a composition with the formula: ABCO, where h is 3&#xb1;10%, i is 2&#xb1;10%, j is 3&#xb1;10%, A includes one or more rare earth elements, B includes aluminum and/or gallium, and C includes aluminum and/or gallium. The method additionally includes consolidating the powder to form an optically transparent ceramic, and applying at least one thermodynamic process condition during the consolidating to reduce oxygen and/or thermodynamically reversible defects in the ceramic. In another embodiment, a scintillator includes (GdY)(GaAl)OD, where a is from about 0.05-2, b is from about 1-3, x is from about 2.8-3.2, y is from about 4.8-5.2, c is from about 0.003-0.3, and D is a dopant, and where the scintillator is an optically transparent ceramic scintillator having physical characteristics of being formed from a ceramic powder consolidated in oxidizing atmospheres.

Transparent ceramic garnet scintillator detector for positron emission tomography

A fluorescent lamp includes a glass envelope; at least two electrodes connected to the glass envelope; mercury vapor and an inert gas within the glass envelope; and a phosphor within the glass envelope, wherein the phosphor blend includes aluminum nitride. The phosphor may be a wurtzite (hexagonal) crystalline structure AlMN phosphor, where M may be drawn from beryllium, magnesium, calcium, strontium, barium, zinc, scandium, yttrium, lanthanum, cerium, praseodymium, europium, gadolinium, terbium, ytterbium, bismuth, manganese, silicon, germanium, tin, boron, or gallium is synthesized to include dopants to control its luminescence under ultraviolet excitation. The disclosed AlMN:Mn phosphor provides bright orange-red emission, comparable in efficiency and spectrum to that of the standard orange-red phosphor used in fluorescent lighting, YO:Eu. Furthermore, it offers excellent lumen maintenance in a fluorescent lamp, and does not utilize 'critical rare earths,' minimizing sensitivity to fluctuating market prices for the rare earth elements.

Fluorescent lighting with aluminum nitride phosphors

In one embodiment, a transparent ceramic of sintered nanoparticles includes gadolinium lutetium oxide doped with europium having a chemical composition (LuGd)EuO, where X is any value within a range from about 0.05 to about 0.45 and Y is any value within a range from about 0.01 to about 0.2, and where the transparent ceramic exhibits a transparency characterized by a scatter coefficient of less than about 10%/cm. In another embodiment, a transparent ceramic scintillator of sintered nanoparticles, includes a body of sintered nanoparticles including gadolinium lutetium oxide doped with a rare earth activator (RE) having a chemical composition (LuGd)REO, where RE is selected from the group consisting of: Sm, Eu, Tb, and Dy, where the transparent ceramic exhibits a transparency characterized by a scatter coefficient of less than about 10%/cm.

Lutetium oxide-based transparent ceramic scintillators

A method for forming a transparent ceramic preform in one embodiment includes forming a suspension of oxide particles in a solvent, wherein the suspension includes a dispersant, with the proviso that the suspension does not include a gelling agent; and uniformly curing the suspension for forming a preform of gelled suspension. A method according to another embodiment includes creating a mixture of inorganic particles, a solvent and a dispersant, the inorganic particles having a mean diameter of less than about 2000 nm; agitating the mixture; adding the mixture to a mold; and curing the mixture in the mold for gelling the mixture, with the proviso that no gelling agent is added to the mixture.

Transparent ceramics and methods of preparation thereof

According to one embodiment, a method for forming a transparent ceramic preform includes forming a suspension of oxide particles in a solvent, adding the suspension to a mold of a desired shape, and uniformly curing the suspension in the mold for forming a preform. The suspension includes a dispersant but does not include a gelling agent. In another embodiment, a method includes creating a mixture without a gelling agent, the mixture including: inorganic particles, a solvent, and a dispersant. The inorganic particles have a mean diameter of less than about 2000 nm. The method also includes agitating the mixture, adding the mixture to a mold, and curing the mixture in the mold at a temperature of less than about 80&#xb0; C. for forming a preform. Other methods for forming a transparent ceramic preform are also described according to several embodiments.

Growing community of inventors

Livermore, CA, United States of America

Zachary M Seeley