Kabushiki Kaisha Toyota Jidoshokki

Yusuke Sugiyama

Nobuhiro Goda

Takeshi Kondo

Masakazu Murase

Masataka Nakanishi

Tomohiro Niimi

Takashi Mohri

Hiroshi Hirate

Takahiro Sugioka

Kazuhito Kawasumi

Hiroki Oshima

Yoshihiro Nakagaki

Yuta Kawamoto

Yuta Nakagawa

Shigenori Koishi

Takashi Mori

Hirotaka Sone

Mutsumi Takahashi

Kohei Mase

Tomokuni Abe

Keigo Oyaizu

Jun Kaneda

Nagisa Watanabe

A polymer compound includes a first chain structure constituted by a polyamideimide and a second chain structure constituted by a vinyl polymer and bonded to terminals of the first chain structures and connecting the first chain structures together. The vinyl polymer constituting the second chain structure is a random copolymer including a bond-constituting unit having a side chain to be bonded to the first chain structure, and a non-bond-constituting unit having no side chain to be bonded to the first chain structure.

Polymer compound, intermediate composition, negative electrode, electricity storage device, and method for producing polymer compound

A polymer compound to be used as a binder for a negative electrode of a power storage device is provided. The polymer compound is formed by condensation of a polyacrylic acid and a polyfunctional amine represented by the following general formula (1), where X is a ring structure having 1 to 3 benzene rings; and Cto Care each a carbon atom constituting a benzene ring in the ring structure. 

Polymeric binder of polyacrylic acid, polyfunctional amine, and linking benzene ring

A negative electrode active material is composed of a silicon material coated with a carbon layer containing a Group 4 to 6 metal. A method for producing a negative electrode active material includes a step of decomposing a compound containing the Group 4 to 6 metal and a carbon source by heating in the presence of a silicon material, the compound, and the carbon source.

Negative electrode active material

A polymer compound, which is used as a binder for a negative electrode of an electricity storage device, is obtained by condensation of a vinyl polymer that contains a carboxyl group and a third compound that is selected from among an aromatic multifunctional amine, phosphorous acid, phosphorous acid ester, trialkoxysilane, and phosphoric acid.

Polymer compound, intermediate composition, negative electrode, electricity storage device, slurry for negative electrodes, method for producing polymer compound, and method for producing negative electrode

A polymer compound is formed by condensing a polyacrylic acid having some of carboxyl groups converted into a lithium salt with a polyfunctional amine represented by the following general formula (1). A chain structure constituted by the polyacrylic acid has free carboxyl groups and carboxyl groups converted into a lithium salt. Y is a straight-chain alkyl group having 1 to 4 carbon atoms, a phenylene group, or an oxygen atom. R1 and R2 are each independently one or more hydrogen atoms, a methyl group, an ethyl group, a trifluoromethyl group, or a methoxy group.

Polymer compound, intermediate composition, negative electrode, electrical storage device, slurry for negative electrode, method for producing polymer compound, and method for producing negative electrode

Cycle characteristics of a nonaqueous secondary battery are to be improved. An active material including: a first active material that contains a nano silicon produced by heating a layered polysilane represented by a composition formula (SiH)and having a structure in which multiple six-membered rings formed from silicon atoms are connected; and a second active material that contains a graphite, is used in a negative electrode. With this, expansion and contraction due to stress during charging and discharging can be mitigated, and thereby cycle characteristics improve.

Negative electrode for nonaqueous secondary battery and nonaqueous secondary battery, negative electrode active material and method for producing same, complex including nano silicon, carbon layer, and cationic polymer layer, and method for producing complex formed of nano silicon and carbon layer

A polymer compound is formed by condensing a polyacrylic acid, a polyfunctional amine represented by the following general formula (1), and an aromatic monoamine. A chain structure constituted by the polyacrylic acid has free carboxyl groups and carboxyl groups to which the aromatic monoamines are bonded. Y is a straight-chain alkyl group having 1 to 4 carbon atoms, a phenylene group, or an oxygen atom. R1 and R2 are each independently one or more hydrogen atoms, a methyl group, an ethyl group, a trifluoromethyl group, or a methoxy group.

Polymer compound formed by condensing polyacrylic acid, polyamine and aromatic monoamine, intermediate composition, negative electrode, electrical storage device, slurry for negative electrode, method for producing polymer compound, and method for producing negative electrode

A nano silicon material having reduced amounts of oxygen (O) and chlorine (Cl) contained therein is provided. The nano silicon material contains fluorine (F) and nano-sized silicon crystallites. Generation of a layer in which oxygen (O) and chlorine (Cl) are present is suppressed due to the presence of fluorine (F), so that a decrease in the moving speed of lithium ions is suppressed. In addition, due to the presence of fluorine (F), the concentrations of oxygen (O) and chlorine (Cl) are reduced, so that reaction thereof with lithium ions is suppressed.

Nano silicon material, method for producing same, and negative electrode of secondary battery

Provided is a negative electrode active material including complex particles formed of: nano silicon aggregated particles produced by heating a layered polysilane represented by a composition formula of (SiH)and having a structure in which multiple six-membered rings formed from silicon atoms are connected; and a composited carbon layer formed from an amorphous carbon and at least covering one portion of the aggregated particles. A mean particle diameter Dof the aggregated particles is within a range of 0.2 &#x3bc;m to 30 &#x3bc;m, and a mean particle diameter Dof the complex particles is within a range of 0.5 &#x3bc;m to 40 &#x3bc;m.

Negative electrode active material, method for producing same, and electrical storage device

A negative-electrode active material is used for a negative electrode, the negative-electrode active material including: agglomerated particles including nanometer-size silicon produced by heat treating a lamellar polysilane having a structure in which multiple six-membered rings constituted of a silicon atom are disposed one after another, and expressed by a compositional formula, (SiH); and a carbon layer including amorphous carbon, and covering at least some of the agglomerated particles to be composited therewith. An electric storage apparatus including the same is not only able to reduce the irreversible capacity, but also able to inhibit the generation of 'SEI.'

Negative-electrode active material, production process for the same and electric storage apparatus

Providing a negative-electrode material for nonaqueous-electrolyte secondary battery, the negative-electrode material including lithium silicate particles coated by a carbonaceous substance, a production process for the same, a negative electrode for nonaqueous-electrolyte secondary battery, and a nonaqueous-electrolyte secondary battery. A negative-electrode material for nonaqueous-electrolyte secondary battery includes lithium silicate particles having a surface at least some of which is coated by a carbonaceous substance formed by heating a carbon-containing compound at a thermal decomposition temperature of the carbon-containing compound or more and 1,100&#xb1;&#xb0; C. or less, the carbon-containing compound being a solid at ordinary temperature and exhibiting a zeta-potential absolute value being 60 or more against N-methyl-2-pyrrolidone (or NMP).

Negative-electrode material for nonaqueous-electrolyte secondary battery production process for the same, negative electrode for nonaqueous-electrolyte secondary battery, and nonaqueous-electrolyte secondary battery

A polymer compound for use as a binder for a negative electrode of an electrical storage device is formed by condensing polyacrylic acid and a multifunctional amine represented by the following formula (1), in which Y represents a straight chain alkyl group having 1 to 4 carbon atoms, a phenylene group, or an oxygen atom, and R1 and R2 each independently represent one or more hydrogen atoms, methyl groups, ethyl groups, trifluoromethyl groups, or methoxy groups. 

High-molecular compound, intermediate composition, negative electrode, electrical storage device, slurry for negative electrode method for producing high-molecular compound, and method for producing negative electrode

A negative-electrode active material is provided, the negative-electrode active material including: a lamellar polysilane having a structure in which multiple six-membered rings constituted of a silicon atom are disposed one after another, and expressed by a compositional formula, (SiH), as a basic skeleton; and the negative-electrode active material containing copper in an amount of from 0.01 to 50% by mass. To contain copper results in upgrading electron conductivity. Consequently, an electric storage apparatus using the negative-electrode active material for one of the negative electrodes has upgraded rate characteristic, and also has augmented charged and discharged capacities.

Negative-electrode active material and electric storage apparatus

A nanometer-size silicon material produced by heat treating a lamellar polysilane exhibits Raman-shift peaks existing at 341&#xb1;10 cm, 360&#xb1;10 cm, 498&#xb1;10 cm, 638&#xb1;10 cm, and 734&#xb1;10 cmin a Raman spectrum, has a large specific surface area, and has a reduced SiO content.

Production process for nanometer-size silicon material

Providing a negative-electrode active material for nonaqueous-electrolyte secondary battery, the negative-electrode active material enabling an output characteristic to upgrade, a production process for the same, a negative electrode for nonaqueous-electrolyte secondary battery, and a nonaqueous-electrolyte secondary battery. The negative-electrode active material includes an Si-metal-carbon composite composed of: a metal/carbon composite matrix including at least one metal selected from the group consisting of Cu, Fe, Ni, Ti, Nb, Zn, In and Sn, at least one member selected from the group consisting of N, O, P and S, and amorphous carbon; and nanometer-size Si particles dispersed in the metal/carbon composite matrix.

Negative-electrode active material for nonaqueous-electrolyte secondary battery production process for the same, negative electrode for nonaqueous-electrolyte secondary battery, and nonaqueous-electrolyte secondary battery

Growing community of inventors

Kariya, Japan

Yusuke Sugiyama