Toyota Jidosha Kabushiki Kaisha

Panasonic Corporation

Matsushita Electric Industrial Co., Ltd.

Panasonic Holdings Corporation

Panasonic Intellectual Property Management Co., Ltd.

Yusuke Fukumoto

Harunari Shimamura

Tatsuya Hashimoto

Yuji Yokoyama

Hiroya Umeyama

Koji Torita

Akihiro Ochiai

Tetsuya Hayashi

Tomoyoshi Ueki

Shigeo Ikuta

Naoyuki Wada

Keisuke Ohara

Kaoru Inoue

Naoto Onodera

Tsumoru Ohata

Kohei Suzuki

Nobuhiro Hirano

Masanori Sugimori

Yo Kato

Takuya Asari

Koichi Toriyama

Junji Nakajima

Kiyomi Kato

Hideki Sano

Keiichi Takahashi

Shuji Tsutsumi

Masahiro Morita

Kouichi Toriyama

Hideaki Fujita

Shinji Kasamatsu

Fumio Kato

Shozo Fujiwara

Akihiro Taniguchi

Takafumi Oura

Hideyuki Saka

Toshihiko Mitsuhashi

Ryo Hanazaki

Akiko Fujino

Akira Nagasaki

Tsuyoshi Hatanaka

Norihiro Yamamoto

Yasuhiko Hina

Tsuyoshi Iwakura

Provided is an electrode slurry carbon nanotube liquid dispersion which improves charge/discharge cycle characteristics. An electrode slurry carbon nanotube liquid dispersion which is one aspect of the present disclosure and contains 0.1-1.5 mass % of carbon nanotubes, a dispersion medium, and carboxymethyl cellulose, the viscosity of which at 100sin a 3% aqueous solution is 2-200 mPa·s, wherein: the carboxymethyl cellulose content constitutes 50-250 parts by mass relative to 100 parts by mass of carbon nanotubes; the viscosity at 100sis 50-200 mPa·s in a state in which the carbon nanotubes are dispersed; and the particle distribution according to the laser diffraction method exhibits a D10 of 0.3-1.0 μm, a D50 of 3-10 μm and a D90 of 60 μm or less in a state in which the carbon nanotubes are dispersed.

Electrode slurry carbon nanotube liquid dispersion, negative electrode slurry, non-aqueous electrolyte secondary battery, and method for producing electrode slurry carbon nanotube liquid dispersion

A negative electrode for a nonaqueous electrolyte secondary battery comprises a negative electrode core body, and a negative electrode mixture layer. When the range of 40% of the thickness of the negative electrode mixture layer from the surface of the negative electrode mixture layer on the side opposite to the negative electrode core body is defined as a first region and the range of 40% of the thickness of the negative electrode mixture layer from the interface between the negative electrode mixture layer and the negative electrode core body is defined as a second region, the BET specific surface area of the graphite included in the first region is smaller than the BET specific surface area of the graphite included in the second region.

Negative electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery

A positive electrode includes at least a positive electrode current collector and a positive electrode active material layer. The positive electrode active material layer is disposed on a surface of the positive electrode current collector. The positive electrode current collector includes an aluminum foil and an aluminum hydrated oxide film. The aluminum hydrated oxide film covers a surface of the aluminum foil. The aluminum hydrated oxide film has a thickness not smaller than 50 nm and not greater than 500 nm. The aluminum hydrated oxide film contains a plurality of types of aluminum hydrated oxides. The ratio of boehmite to the plurality of types of aluminum hydrated oxides is not lower than 20 mol % and not higher than 80 mol %.

Positive electrode, non-aqueous electrolyte secondary battery, and method of producing positive electrode

A negative electrode for a nonaqueous electrolyte secondary battery, which is an example of embodiments, comprises a negative electrode core body and a negative electrode mixture layer provided on the surface of the negative electrode core body. The negative electrode mixture layer includes graphite and fibrous carbon. The BET specific surface area of the graphite included in the first region is smaller than the BET specific surface area of the graphite included in the second region. In addition, the average length of the fibrous carbon included in the second region is longer than the average length of the fibrous carbon included in the first region.

A negative electrode for a nonaqueous electrolyte secondary battery, which is an example of embodiments, comprises a negative electrode core body and a negative electrode mixture layer provided on the surface of the negative electrode core body. The negative electrode mixture layer includes graphite and fibrous carbon. The BET specific surface area of the graphite included in the first region is smaller than the BET specific surface area of the graphite included in the second region. In addition, the average length of the fibrous carbon included in the first region is longer than the average length of the fibrous carbon included in the second region.

A negative electrode for a nonaqueous electrolyte secondary battery comprises a negative electrode core body and a negative electrode mixture layer provided. When the range of 40% of the thickness of the negative electrode mixture layer from the surface of the negative electrode mixture layer is defined as a first region and the range of 40% of the thickness of the negative electrode mixture layer from the surface of the negative electrode core body is defined as a second region, the BET specific surface area of the graphite included in the first region is smaller than that of the graphite included in the second region. The first region includes the multiwalled fibrous carbon more than the single wall fibrous carbon in terms of mass and the second region includes the single wall fibrous carbon more than the multiwalled fibrous carbon in terms of mass.

A nonaqueous battery includes a positive electrode and a negative electrode. At least one of the positive electrode and the negative electrode includes a current collector, an intermediate layer, and an active material layer. The intermediate layer is interposed between the current collector and the active material layer and includes graphite particles and insulating particles. In a cross section of the intermediate layer in a thickness direction, a major axis diameter of the graphite particles is equal to or greater than the thickness of the intermediate layer. In X-ray diffraction measurement of the intermediate layer by an out-of-plane method, a ratio of an intensity of an 110 diffraction line of a graphite crystal to an intensity of a 002 diffraction line of the graphite crystal is 0.0011 or more.

Nonaqueous battery and method of producing the same

A positive electrode includes at least a positive electrode current collector and a positive electrode active material layer. The positive electrode active material layer is formed on a surface of the positive electrode current collector. The positive electrode current collector includes an aluminum foil and a porous film. The porous film covers a surface of the aluminum foil. The porous film contains at least aluminum oxide. The porous film has a thickness not smaller than 10 nm and not greater than 800 nm. The porous film has a dynamic hardness not lower than 5 and not higher than 200.

Positive electrode, lithium-ion secondary battery, and method of producing positive electrode

A positive electrode includes at least a positive electrode current collector, a conductive material, and a positive electrode active material. The positive electrode active material is disposed on a surface of the positive electrode current collector. The positive electrode current collector includes an aluminum foil and an aluminum oxide hydrate film. The aluminum oxide hydrate film covers a surface of the aluminum foil. The aluminum oxide hydrate film has a thickness not smaller than 10 nm and not greater than 500 nm. The aluminum oxide hydrate film has a porosity not lower than 10% and not higher than 50%. At least part of the conductive material is disposed within pores in the aluminum oxide hydrate film.

A battery includes an electrode plate group. The electrode plate group includes electrode plates and a separator. The electrode plate group is obtained by laminating a plurality of electrode plates. The separator is disposed between the electrode plates. A surface of at least one of the electrode plates is a particle layer. A surface of the separator is a nonwoven fabric layer. The particle layer includes fibrous particles. The particle layer and the nonwoven fabric layer are in contact with each other.

Battery

A positive electrode includes at least a positive electrode current collector and a positive electrode active material layer. The positive electrode current collector includes an aluminum foil and an aluminum hydrated oxide film. The aluminum hydrated oxide film covers a surface of the aluminum foil. The positive electrode active material layer is formed on a surface of the aluminum hydrated oxide film. The aluminum hydrated oxide film has a thickness not smaller than 50 nm and not greater than 1000 nm. The aluminum hydrated oxide film contains at least one selected from the group consisting of phosphorus, fluorine, and sulfur.

A non-aqueous electrolyte secondary battery includes at least a positive electrode, a negative electrode, and an electrolyte. The positive electrode includes a positive electrode current collector, an intermediate layer, and a positive electrode active material layer. The intermediate layer is interposed between the positive electrode current collector and the positive electrode active material layer. The intermediate layer contains at least carboxymethylcellulose, a conductive material, and an inorganic filler.

Non-aqueous electrolyte secondary battery having positive electrode including carboxymethylcellulose, polymer binder, conductive material, and inorganic filler

A separator is for a non-aqueous electrolyte secondary battery. The separator includes at least a porous film. The porous film contains a resin composition. The resin composition contains a thermoplastic resin and metal hydroxide particles.

Separator including thermoplastic resin and metal hydroxide particles, non-aqueous electrolyte secondary battery, and method of manufacturing separator

A flat-plate portion of a negative electrode composite material layer includes a first end portion at one end portion in a direction of axis of winding of a flat electrode winding assembly, a second end portion located opposite to the first end portion, and a central portion lying between the first end portion and the second end portion. The flat-plate portion of the negative electrode composite material layer is provided with a plurality of communication grooves. The communication groove includes a first terminal end portion at the first end portion, includes a second terminal end portion at the second end portion, includes in the central portion, a starting portion located closer to a bottom portion of a prismatic case relative to the first terminal end portion and the second terminal end portion, and extends from the starting portion toward the first terminal end portion and the second terminal end portion.

Non-aqueous electrolytic secondary battery and method of manufacturing the same

A positive electrode for a non-aqueous electrolyte secondary battery includes a positive electrode current collector, a protective layer provided on a surface of the positive electrode current collector, and a positive electrode composite material layer containing a positive electrode active material provided on a surface of the protective layer. The protective layer includes an insulating filler, a binder, and a conductive material. The protective layer is composed of a central portion and an end portion in a plan view as seen from the stacking direction. The ratio of the conductive material in the end portion of the protective layer is smaller than the ratio of the conductive material in the central portion of the protective layer. The ratio Sc/S of the area Sc of the end portion of the protective layer to the total area S of the protective layer in plan view is 0.12 or more.

Growing community of inventors

Toyonaka, Japan

Yusuke Fukumoto