Idemitsu Kosan Company, Limited

Yusuke Aoki

Yasuhiro Ishikawa

Takayoshi Tanaka

Masami Takimoto

Aki Yamada

Yoshio Okamoto

Tsuyoshi Murakami

Noritada Takeuchi

Provided is a polycarbonate-based resin composition containing a polycarbonate-based resin containing a predetermined polycarbonate-polyorganosiloxane copolymer, and 0.5 to 5 parts by mass of a white pigment with respect to 100 parts by mass of the polycarbonate-based resin, in which the molecular weight distribution of a polyorganosiloxane block in the polycarbonate-polyorganosiloxane copolymer is controlled within a specific region.

Polycarbonate-based resin composition and molded article thereof

Provided is a polycarbonate resin molding material for articles to be coated, containing a polycarbonate resin (A) containing a polycarbonate-polyorganosiloxane copolymer (A-1) having a specific structure, and a copolymer (B) having a constituent unit derived from butadiene, and a content of the polyorganosiloxane block moiety in entirety of the molding material is in the range of 0.50 to 10% by mass and a content of the constituent unit derived from butadiene in entirety of the molding material is in the range of 1 to 10% by mass.

Polycarbonate resin molding material for articles to be coated, molded article and coated molded article

Provided is a polycarbonate-based resin composition, including, with respect to 100 parts by mass of (A) a resin mixture formed of 30 to 100 mass % of a polycarbonate-polyorganosiloxane copolymer (A-1) having a structural unit represented by the general formula (I) and a structural unit represented by the general formula (II), and having an average number of repetitions n of an organosiloxane constituent unit in the general formula (II) of 50 to 500, and 0 to 70 mass % of an aromatic polycarbonate (A-2) except the copolymer (A-1), 1 to 5.5 parts by mass of (B) a polyorganosiloxane-acrylic composite rubber, the composition having a viscosity-average molecular weight of 17,000 to 23,000. Also provided is a molded article thereof. 

Polycarbonate resin composition and molded article

Provided is a polycarbonate resin composition, including: 100 parts by mass of (A) a resin mixture including a specific polycarbonate-polyorganosiloxane copolymer (A-1) and a specific polycarbonate-polyorganosiloxane copolymer (A-2), the component (A) having a content of the siloxane unit in the polycarbonate-polyorganosiloxane copolymer (A-1) of 1.0 mass % to 15.0 mass % and having a content of a siloxane unit in the polycarbonate-polyorganosiloxane copolymer (A-2) of 0.1 mass % to 2.8 mass %; and 0.01 to 0.08 part by mass of (B) at least one kind selected from an alkali metal salt of an organic sulfonic acid and an alkali earth metal salt of an organic sulfonic acid.

Polycarbonate resin composition and molded body

Provided is a polycarbonate resin composition including, with respect to 100 parts by mass of an aromatic polycarbonate resin mixture (A) consisting of 5 to 100 mass % of an aromatic polycarbonate-polyorganosiloxane copolymer (A-1) and 95 to 0 mass % of an aromatic polycarbonate resin (A-2) except the component (A-1), the aromatic polycarbonate resin mixture (A) having a content of a polyorganosiloxane unit is 1 mass % or more, 0.002 to 0.200 parts by mass of a phosphorus-based antioxidant (B) and 0 to 0.200 parts by mass of an epoxidation stabilizer (C), in which a reduction ratio P between the viscosity-average molecular weights of the resin composition before and after a pressure cooker test calculated from the calculation equation (I) is 20% or less. The polycarbonate resin composition can be a material for a molded body capable of maintaining its excellent impact-resisting performance at low temperatures for a long time period even when repeatedly used under a high-temperature and high-humidity environment, and its discoloration or the like hardly occurs even when the resin composition is retained at high temperatures.

Provided are a polycarbonate-based resin composition that brings together an excellent impact strength and excellent flame retardancy and a molded article thereof. The polycarbonate-based resin composition is a polycarbonate-based resin composition, including, with respect to 100 parts by mass of (A) a resin mixture formed of 30 to 100 mass % of (A-1) a polycarbonate-polyorganosiloxane copolymer which has a constituent unit represented by a general formula (I) and a constituent unit represented by a general formula (II), and in which an average number of repetitions of the constituent unit represented by the general formula (II) is 30 to 500, and 70 to 0 mass % of (A-2) an aromatic polycarbonate resin except the polycarbonate-polyorganosiloxane copolymer, 0.01 to 0.15 part by mass of (B) an alkali metal salt and/or alkaline earth metal salt of an organosulfonic acid, and 0.1 to 1 part by mass of (C) a mixed powder formed of polytetrafluoroethylene particles and organic polymer particles, in which: a content of a polyorganosiloxane block moiety formed of the constituent unit represented by the general formula (II) in the resin mixture (A) is 2 to 30 mass %; and the composition is free of an organohalogen-based flame retardant and an organophosphate-based flame retardant.

A current breaker case including a polycarbonate resin composition that includes a polycarbonate-polyorganosiloxane copolymer and has a viscosity-average molecular weight of 18000 to 25000.

Current breaker case and current breaker using the same

Provided are: a polycarbonate-based resin composition, including: (A) 100 parts by mass of a resin mixture formed of: 30 to 100 mass % of a PC-POS copolymer (A-1) which has constituent units represented by a general formula (I) and a general formula (II), and in which an average repetition number n of organosiloxane constituent units in the general formula (II) is 70 to 500; and 70 to 0 mass % of an aromatic polycarbonate resin (A-2) except the PC-POS copolymer (A-1); (B) 0.01 to 0.15 part by mass of an alkaline (earth) metal salt of an organic sulfonic acid; (C) 0.1 to 1 part by mass of a polytetrafluoroethylene having a fibril-forming ability; and (D) 2 to 15 parts by mass of titanium dioxide particles each having, on an outermost surface thereof, a coating layer formed of a polyol free of a nitrogen atom; a molded article obtained by molding the resin composition; and a structure member for solar photovoltaic power generation formed of the molded article. The polycarbonate-based resin composition, molded article, and structure member for solar photovoltaic power generation each have excellent flame retardancy and excellent tracking resistance without impairing a low-temperature impact characteristic which a PC-POS copolymer has.

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Chiba, Japan

Yusuke Aoki