China Petroleum Chemical Corporation

Research Institute of Petroleum Processing, Sinopec

Yusi Liu

Huiguo Wang

Ningning Gao

Jianfeng Ma

Dehua Wang

Ben Li

Yanqiang Yang

Hongchao Wang

Xiaofei Qiao

The present invention provides a composite layer agglomerating adsorbent, comprising an outer adsorbent layer containing a low silica X molecular sieve and an inner adsorbent layer containing a high silica X molecular sieve, the low silica X molecular sieve has a silica/alumina molar ratio of 2.07-2.18, the high silica X molecular sieve has a silica/alumina molar ratio of 2.2-2.5, based on the total amount of the adsorbent, the adsorbent comprises 95.0-100 mass % of the X molecular sieve and 0-5.0 mass % of the matrix, the cation sites of the X molecular sieve in the adsorbent are occupied by a metal of Group IIA or occupied together by a metal of Group IA and a metal of Group IIA. The adsorbent is suitable for the process of adsorptive separation of PX from Caromatic hydrocarbons using light aromatic hydrocarbons as desorbent, and has high adsorption selectivity and good mass transfer performance.

Composite layer agglomerating adsorbent and preparation process thereof

A process for producing para-xylene and ethylbenzene from Caromatics containing ethylbenzene includes the steps of sending Caromatics containing ethylbenzene to an ethylbenzene liquid-phase adsorption separation device, wherein a suction liquid containing ethylbenzene and a suction residual liquid are obtained after the adsorption separation, and the desorbents in the suction liquid and the suction residual liquid are removed to obtain ethylbenzene and a suction residual oil; sending the suction residual oil to a para-xylene adsorption separation device, and unadsorbed components are discharged as a raffinate from the adsorbent bed; the adsorbent bed is rinsed with a desorbent to desorb the para-xylene therein and obtain an extract; the desorbents in the extract and the raffinate are respectively removed to obtain para-xylene and a raffinate oil; sending the raffinate oil to a xylene isomerization device to carry out xylene isomerization, and the isomerization product is fractionated.

Process for producing p-xylene and ethylbenzene from Caromatic containing ethylbenzene

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Beijing, China

Yusi Liu