Lg Chem, Ltd

Yun Kon Kim

Ki Soo Lee

Eun Ji Shin

Seok Pil Sa

Seul Ki Im

Ji Hyun Park

Hyun Mo Lee

Seung Jung Yu

Myung Han Lee

Mi Kyung Kim

Sung Hyun Park

Dae Woong Lee

Tae Hee Kim

Dong Min Kim

The present invention relates to a method for preparing a polyolefin-polystyrene-based multiblock copolymer having a uniform structure and showing excellent physical properties through continuous type coordination polymerization and batch type anionic polymerization.

Method for preparing polyolefin-polystyrene-based multiblock copolymer

The present invention relates to a thermoplastic resin composition including a polyolefin-polystyrene-based multi-block copolymer having a structure in which a polystyrene chain is attached to both ends of a polypropylene and polyolefin chain, and the thermoplastic resin composition according to the present invention exhibits high fluidity properties as well as soft feel and high restoring force.

Thermoplastic resin composition

A polyolefin-polystyrene multi-block copolymer and a method of producing the same is disclosed herein. In some embodiments, the polyolefin-polystyrene multi-block copolymer has a first complex viscosity of 40,000 Pa·s to 350,000 Pa·s at a temperature of 160° C. and a first frequency of 0.5 rad/s, and has a second complex viscosity of 900 Pa·s to 3,500 Pa·s at a temperature of 160° C. and a second frequency of 125 rad/s. The polyolefin-polystyrene multi-block copolymer has a structure in which polystyrene chains are attached to both ends of a polyolefin chain.

Polyolefin-polystyrene multi-block copolymer and method for producing same

A polyolefin-polystyrene multi-block copolymer and method of making the same is disclosed herein. In some embodiments, a polyolefin-polystyrene multi-block copolymer having a ratio of a loss modulus (E″) to a storage modulus (E') satisfying the following conditions (a) and (b) over a temperature range of −80° C. to 40° C., wherein the ratio is represented by a loss tangent (tan δ) value and is obtained by dynamic mechanical analysis (DMA), (a) a maximum of the tan δ value in a peak present in the temperature range is 0.20 to 0.35, and (b) a half-width of the peak ranges from 32.0° C. to 50.0° C. The polyolefin-polystyrene multi-block copolymer has a structure in which polystyrene chains are attached to both ends of a polyolefin chain.

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Daejeon, South Korea

Yun Kon Kim