Lg Chem, Ltd

Yun Ki Cho

Hyun Kyu Kim

Jeong Ju Moon

Joo Ho Kim

Seok Ho Jeong

Mi Yeon Lee

Woo Hyuk Choi

Seung Young Park

Yoon Jung Kim

Taek Jun Jung

Jin Woo Lee

Yong Hee An

Bo Hyun Seong

Jung Min Sohn

Jun Wye Lee

Hyun Min Kim

Hyun Ju Cho

Sung-Kyoung Kim

The present disclosure relates to a plasticizer composition characterized in including two or more isophthalates of the same carbon number type, in which alkyl groups bonded to two ester groups have the same carbon number; one or more isophthalates of a different carbon number type, in which alkyl groups bonded to two ester groups have different carbon numbers; wherein the different carbon number type includes both a higher alkyl and a lower alkyl, the carbon number of the higher alkyl is 8 to 10, and the carbon number of the lower alkyl is selected from 5 to 7, thereby, when applied to a resin, showing improved viscosity stability, migration resistance and stress resistance, while maintaining and improving plasticization efficiency and mechanical properties to the same or better level.

Plasticizer composition and resin composition including the same

The present disclosure relates to a plasticizer composition including a cyclohexane 1,4-diester-based material and a cyclohexane 1,2,4-triester-based material, and may provide a plasticizer maintaining an excellent level of plasticization efficiency when compared with a common phthalate-based plasticizer product and improving mechanical properties, and may also provide a plasticizer having excellent stress resistance as an advantage.

Provided is a plasticizer composition, comprising: two or more kinds of terephthalates of the same carbon number type, wherein the carbon number of alkyl groups bonded to two ester groups is the same; and one or more kinds of terephthalates of a different carbon number type, wherein the carbon number of alkyl groups bonded to two ester groups is different, the different carbon number type comprises a higher alkyl and a lower alkyl, the higher alkyl is selected from alkyl groups having a carbon number of 8 or less, and the lower alkyl is selected from alkyl groups having a carbon number of 5 or more.

A plasticizer composition which includes a lower non-hybrid-type cyclohexane triester, a lower hybrid-type cyclohexane triester, a higher hybrid-type cyclohexane triester, and a higher non-hybrid-type cyclohexane triester, wherein the alkyl groups of the cyclohexane triesters are a combination of C3-C6 alkyl groups and C7-C10 alkyl groups. When the plasticizer composition is applied to a resin, stress resistance and mechanical properties are maintained at an equivalent level or improved, migration properties, volatile loss characteristics, and plasticization efficiency are balanced, and light resistance and heat resistance are significantly improved.

Cyclohexane triester based plasticizer composition and resin composition comprising the same

Provided is a plasticizer composition including a cyclohexane-1,2-diester-based material of Formula 1 and a trimellitate-based material of Formula 2:

A plasticizer composition and a resin composition including the plasticizer composition. The resin composition addresses limitations associated with conventional plasticizers by improving various properties such as plasticization efficiency and mechanical properties including migration properties, volatile loss, tensile strength and elongation rate. The plasticizer composition is also capable of improving properties such as elongation retention and cold tolerance.

Provided is a plasticizer composition, including: a cyclohexane-1,2-diester-based substance in which two alkyl groups are bonded to the ester groups, and the alkyl groups each independently are a C4 to C12 alkyl group; and an epoxidized alkyl ester composition comprising one or more compounds of the following Chemical Formula 1:

Provided is a plasticizer composition, comprising: a cyclohexane-1,4-diester-based substance of the following Chemical Formula 1; an epoxidized alkyl ester composition comprising one or more compounds of the following Chemical Formula 2; and a citrate-based substance of the following Chemical Formula 3:

The present invention relates to a plasticizer composition in which three types of cyclohexane 1,4-diester-based compounds prepared through trans-esterification and hydrogenation are mixed, wherein alkyl substituents of the dicarboxylate are a 2-ethylhexyl group and a butyl group or an isobutyl group, which has fewer carbon atoms than the 2-ethylhexyl group, so that the plasticizer composition may exhibit excellent properties in terms of stress resistance, migration resistance, plasticization efficiency, and the like while maintaining an excellent level of tensile strength and elongation rate, when used for a resin composition.

Plasticizer composition including cyclohexane 1,4-diester-based compound and resin composition including the same

A plasticizer composition, and a resin composition including the same. The plasticizer composition includes 70 to 99 wt % of a first plasticizer including a terephthalate-based material and a citrate-based material in a specific weight ratio; and 1 to 30 wt % of a second plasticizer including an epoxidized alkyl ester composition. The plasticizer composition has enhanced physical properties, such as thermal stability and light resistance. In addition, the plasticizer composition has stable and improved tensile and elongation properties, migration resistance and volatile loss.

Provided is a plasticizer composition including: a cyclohexane-1,2-diester-based substance of the following Chemical Formula 1; and a citrate-based substance of the following Chemical Formula 2: 

The present invention relates to a plasticizer composition and a resin composition including the same. The compositions comprise a terephthalate-based material, a dibenzoate-based material, and a citrate. The compositions and methods have a weight ratio of the terephthalate-based material to the benzoate-based material of 99:1 to 1:99. The citrate-based material is included at 1 to 80 parts by weight with respect to 100 parts by weight of the total weight of the terephthalate-based material and the dibenzoate-based material.

Provided is a citrate-based plasticizer and a resin composition including the same. The citrate-based plasticizer includes one or more citrates having alkyl groups with 7 carbon atoms. The citrate-based plasticizer can solve limitations on migration and volatile loss inherent in the conventional plasticizer and limitations on characteristics of processing such as plasticizing efficiency and absorption rate.

Citrate-based plasticizer and resin composition including the same

A plasticizer composition, a resin composition and methods of preparing the same are disclosed. The compositions and methods comprise a terephthalate-based material, which has two alkyl groups bound to a diester group, and a dibenzoate-based material. The compositions and methods have a weight ratio of the terephthalate-based material to the dibenzoate-based material of 99:1 to 1:99.

Plasticizer composition, resin composition and methods of preparing the same

Provided are a plasticizer composition, a resin composition and a method of preparing the same. Particularly, a plasticizer comprising a cyclohexane 1,4-diester based material and a citrate-based material. The plasticizer is capable of improving physical properties such as plasticization efficiency, migration, tensile strength, elongation rate, stress migration and light fastness, which are required for sheet formulations, when used as a plasticizer for the resin composition by improving poor physical properties generated due to a structural limitation thereof, and a resin composition including the same are provided.

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Daejeon, South Korea

Yun Ki Cho