Korea Research Institute of Chemical Technology

Daelim Industrial Co., Ltd.

Korea National Oil Corporation

Sk Innovation Co., Ltd.

Industry-university Cooperation Foundation Sogang University

Korea Gas Corporation

Hyundai Engineering Co. Ltd.

Sogang University Corporation

Yun-Jo Lee

Ki-Won Jun

Jong-Wook Bae

Seung-Moon Kim

Kyung Byung Yoon

Jin-Seok Lee

Yong-Soo Park

Kwang Rim Ha

Kyung-Byung Yoon

Jong-San Chang

Jin Seok Lee

Sang-Eon Park

Yong Soo Park

Yong Soo Chang

Goo-Soo Lee

Suk-Hwan Kang

Jo Yong Park

Yu-Sung Chun

Eunju Lee Tae

Gyung-Mi Kim

Seong-Hee Han

Hyo Jean Kim

The present invention relates to a process of preparing of a phosphorus-containing phosphorus-alumina support by a sol-gel method and a cobalt/phosphorus-alumina catalyst where cobalt is supported onto the phosphorus-alumina support as an active ingredient. The phosphorus-alumina support is prepared by a sol-gel method and has wide specific surface area with bimodal pore size distribution and high cobalt dispersion, thereby enabling to increase heat and mass transfer, stabilize the structure by modifying the surface property of alumina and decrease the deactivation rate due to the reduced oxidation of cobalt component during the F-T reaction. When Fischer-Tropsch reaction (F-T) is conducted on the catalyst, the catalyst maintains a superior thermal stability, inhibits the deactivation due to water generation during the F-T reaction and also causes relatively high conversion of carbon monoxide and stable selectivity of liquid hydrocarbons.

Preparing phosphorus containing alumina support by sol-gel method for Fischer-Tropsch synthesis and catalyst preparation thereof

Preparing phosphorus containing alumina support by sol-gel method for fischer-tropsch synthesis and catalyst preparation thereof

The present invention relates to a process for producing light olefins from a synthesis gas with significantly improved conversion and selectivity for C-Clight olefins in general and propylene in particular, as compared to a conventional process, through a sequential two-step process comprising preparing olefin compounds from a synthesis gas in the presence of an iron catalyst by the Fischer-Tropsch reaction followed by cracking the olefin compounds in the presence of a zeolite catalyst.

Process for producing light olefins from synthesis gas using dual sequential bed reactor

The present invention relates to a method for preparing substrate-molecular sieve layer complex by vising ultra-sound and apparatuses used therein, more particularly to a method for preparing substrate-molecular sieve layer complex by combining substrate, coupling compound and molecular sieve particle, wherein covalent, ionic, coordinate or hydrogen bond between a substrate and a coupling compound; molecular sieve particle and coupling compound; coupling compounds; coupling compound and intermediate coupling compound is induced by using 15 KHz-100 MHz of ultrasound instead of simple reflux to combine substrate and molecular sieve particles by various processes, further to reduce time and energy, to retain high binding velocity, binding strength, binding intensity and density remarkably, to attach molecular sieve particle uniformly onto all substrates combined with coupling compound selectively, even though substrate with coupling compound and substrate without coupling compound exist together; and apparatuses installed therein, which can improve to produce substrate-molecular sieve layer complex in a large scale.

Method of preparing substrates&#x2014;molecular sieve layers complex using ultrasound and apparatuses used therein

The present invention relates to a cobalt/phosphorus-alumina catalyst in which cobalt is supported as an active component on a phosphorus-alumina support wherein phosphorus is supported on alumina surface. With a bimodal pore structure of pores of relatively different pore sizes, the catalyst provides superior heat- and matter-transfer performance and excellent catalytic reactivity. Especially, when Fischer-Tropsch (F-T) reaction is performed using the catalyst, deactivation by the water produced during the F-T reaction is inhibited and, at the same time, the dispersion and reducing property of cobalt and other active component are improved. Therefore, the cobalt/phosphorus-alumina catalyst for F-T reaction in accordance with the present invention provides good carbon monoxide conversion and stable selectivity for liquid hydrocarbons.

Catalysts for fischer-tropsch synthesis on cobalt/phosphorus-aluminum oxide and preparation methods thereof

The present invention relates to a method for preparing a uniformly aligned zeolite supercrystal, which comprises growing a crystal of a zeolite or zeotype material in a uniformly aligned template, whereby said uniformly aligned zeolite supercrystal is prepared, and a uniformly aligned zeolite supercrystal. The uniformly aligned zeolite supercrystal of this invention would be anticipated to maximize its applicability by overcoming the shortcomings of zeolites with random orientation.

Method for preparation of uniformly oriented zeolite supercrystals using uniformly aligned template

The present invention provides a macroporous foam comprising microporous zeolite or zeotype material and preparation thereof, which comprises dipping a polymeric template capable of releasing an amine which has a sponge or macroporous structure and can be selected from a group consisting of polyurethane, polyamides, aromatic or aliphatic polyimides, polyamideimides, epoxy resins having an amine skeleton, and polymeric materials capable of releasing an organic amine by hydrolysis, in an alkaline or acidic solution, gel or sol of a precursor of said zeolite or zeotype material, and reacting the resultant at a suitable temperature for a period such that all or almost all of the polymeric template can be replaced with zeolite or zeotype material. Said foam comprising zeolite or zeotype material has the outer shape and size and the inner sponge or macroporous structure which are the same or similar to those of the polymeric template used.

Method of the preparation of macroporous foam comprising zeolite or zeotype material

The present invention relates to a method for the preparation of a zeolite-substrate composite comprising a patterned zeolite monolayer or multilayer on a substrate, which comprises forming a pattern of a linking compound on the substrate by a selective irradiation with a UV ray, a selective application of a linking compound or a blocking compound, or a selective deposition of a metal, and combining zeolite particles on the portion whereon the linking compound is patterned. The substrate is selected from a group consisting of a substrate having surface hydroxyl groups, a metal capable of being reacted with thiol or amino groups, and a polymeric material having various surface functional groups. The present invention also relates to a zeolite-substrate composite comprising a patterned zeolite monolayer or multilayer on a substrate prepared by said method.

Zeolite-substrate composite comprising a patterned zeolite layer on a substrate and preparation thereof

The present invention provides a catalyst for reduction of nitrogen oxides represented by the formula (A.sub.a O.sub.x.B.sub.b O.sub.y).(C.sub.c O.sub.z.C'.sub.c' O.sub.z')/S which is produced by supporting mixed metal oxides represented by the formula (A.sub.z O.sub.x.B.sub.b O.sub.y).(C.sub.c O.sub.z.C'.sub.c' O.sub.z') in amorphous state on aluminum or silicon-containing support at calcination temperature of 400.degree. to 700.degree. C. in a molar ratio of 0.01:1 to 5:1, and a method for removing nitrogen oxides through selective catalytic reduction which comprises converting 50 to 50,000 ppm of nitrogen oxides in exhaust gas from automobile or from fixed source such as plant turbine and boiler, and other industry in a state of having 0.1 to 20% of excessive oxygen over (A.sub.a O.sub.x.B.sub.b O.sub.y).(C.sub.c O.sub.z.C'.sub.c' O.sub.z')/S catalyst by using 100 to 100,000 ppm of hydrocarbon reducing agent having 1 to 5 carbons under the reaction condition of 200.degree. to 800.degree. C. of reaction temperature, 1 to 10 atmosphere of reaction pressure and 1000 to 100,000/hour of space velocity into nitrogen in which A and B are lanthanide metals, such as lanthanum, cerium, praseodymium or neodymium, and alkali metals or alkaline earth metals, such as sodium, potassium, rubidium, cesium, magnesium, calcium, strontium or barium, C and C' are transition metals of the first period, such as cobalt, copper, nickel, manganese, iron, vanadium, titanium, chromium and zinc, and noble metals, such as platinum, rhodium, iridium, ruthenium, rhenium, palladium and silver, a, b, c and c' have stoichiometrically 0 to 1, provided with a+b=1, c+c'=1 and is in the range of 0.1-3.0:1.0, and S is aluminum or silicon-containing support, and is zeolite, silica, alumina or silica-alumina.

Method for removing nitrogen oxides in exhaust gas by selective

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Seoul, South Korea

Yun-Jo Lee