Nihon Tokushu Noyaku Seizo K.k.

Nihon Bayer Agrochem, K.k.

Bayer Cropscience Ag

Yumi Hattori

Koichi Moriya

Katsuhiko Shibuya

Shinichi Tsuboi

Kozo Shiokawa

Shoko Sasaki

Ikuro Honda

Shinzaburo Sone

Shin-ichi Tsuboi

Katsuaki Wada

Yuichi Otsu

Fritz Maurer

Shinzo Kagabu

Haruko Sawada

Yoshio Kurahashi

Yoshinori Kitagawa

Takahisa Abe

Toru Obinata

Sinichi Tsuboi

Sakae Murata

Reiner Fischer

Wolfram Andersch

Toshio Goto

Wolfgang Thielert

Toyohiko Kume

Seishi Ito

Shinji Sakawa

Kunihiro Isono

Yoshiko Kyo

Toshihito Kondo

Dirk Ebbinghaus

Jürgen Kühnhold

Kaori Kido

Keiko Tanaka

Shiokawa Kozo

Compounds of the formulae (I) and (II) for controlling pathogens by drenching or drip application.

Use of tetramic acid derivatives for controlling pests by watering or droplet application

Novel benzophenonehydrazone derivatives represented by the formula (I): ##STR1## wherein, R.sup.1 is halogen; R.sup.2 is hydrogen or C.sub.1-4 alkyl; R.sup.3 is cyano, optically substituted C.sub.1-4 alkyl, C.sub.2-4 alkenyl, C.sub.3-4 alkynyl, C.sub.1-4 alkyl-carbonyl or C.sub.1-4 alkoxy-thiocarbonyl; R.sup.4 is hydrogen, phenyl, optionally substituted C.sub.1-6 alkyl, optionally substituted C.sub.2-8 alkenyl, --CO--R.sup.8, --CO--O--R.sup.9 or ##STR2## R.sup.5 is hydrogen, formyl, phenyl, optionally substituted C.sub.1-8 alkyl, optionally substituted C.sub.2-8 alkenyl, optionally substituted C.sub.3-8 alkynyl, optionally substituted C.sub.1-8 alkyl-arbonyl, optionally substituted C.sub.1-6 alkyl-oxalyl, optionally substituted C.sub.1-8 alkoxy-carbonyl, optionally substituted C.sub.1-8 alkoxy-oxalyl, optionally substituted C.sub.3-8 cycloalkyl-carbonyl, optionally substituted C.sub.2-8 alkenyl-carbonyl or optionally substituted benzoyl; R.sup.6 is hydrogen or halogen; R.sup.7 is hydrogen, halogen or C.sub.1-2 alkyl, C.sub.1-4 alkyl-carbonyl or C.sub.1-4 alkoxy-thiocarbonyl; n is 0, 1 or 2, provided that n is 0 when R.sup.3 is cyano, C.sub.1-4 alkyl-carbonyl or C.sub.1-4 alkoxy-thiocarbonyl, is a single bond of Anti form or of Syn form. The benzophenonehydrazone derivatives of the formula (I) have excellent insecticidal activities.

Benzophenone hydrazone derivatives as insecticides

The present invention relates to novel 1-Phenyl-5-anilinotetrazoles of the formula (I): ##STR1## wherein, R.sup.1, R.sup.2, R.sup.3, R.sup.4, m and n have the meaning provided in the specification, precesses for their preparation and their use as microbiocides, insecticides and/or herbicides.

1-phenyl-5-anilinotetrazoles

Insecticidal heterocyclic compounds of the formula ##STR1## wherein A represents a five-membered or six-membered heteroaryl group containing one to three hetero atoms selected from the group consisting of S, O and N, said heteroaryl group being unsubstituted or substituted by a halogen atom or C.sub.1-4 alkyl group, Z represents a three-membered straight chain, each member being selected from the group consisting of CH.sub.2 --, O, S and N--R.sup.2 with at least one of said three members being O, S or N--R.sup.2, E represents CH.sub.2, O, S or N--R.sup.2, wherein R.sup.2 represents a hydrogen atom, a C.sub.1-4 alkyl group, a C.sub.1-4 alkoxy group or the group ##STR2## wherein R.sup.3 represents a hydrogen atom or halogen atom, X represents CH or N, Y represents a nitro group or cyano group, and R.sup.1 represents a hydrogen atom or methyl group.

Insecticidal heterocyclic compounds

Nitro-substituted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl,

Nitro-substituted heterocyclic compounds

Novel pesticidal sulfamide derivatives of the formula ##STR1## in which X is halogen or C.sub.1 -C.sub.4 -halogenoalkyl, R.sup.1 is C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -halogenoalkyl, R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, and R.sup.3 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.4 -alkoxycarbonylmethyl.

Sulfamide derivatives

Novel guanidine derivatives of the formula (I) ##STR1## wherein Z is 2-chloro-5-pyridyl, 2-chloro-5-thiazolyl, or 3-chloro-5-isoxazolyl, R.sup.1 is hydrogen or C.sub.1-4 alkyl, R.sup.2 is hydrogen, C.sub.1-4 alkyl, C.sub.3-4 alkynyl, C.sub.3-4 alkenyl or 2-chloro-5-pyridylmethyl, R.sup.3 and R.sup.4 each represent hydrogen, halogen, C.sub.1-4 alkyl, C.sub.3-4 alkynyl, C.sub.3-4 alkenyl, benzyl which may be substituted, or Z--C(R.sup.1)H-, n is 2 or 3, and Y is nitro or cyano, and pesticidal compositions comprising the compound of the formula (I) as active components.

Insecticidal guanidine derivatives

Insecticidal guanidine derivatives of the formula ##STR1## wherein Z represents an optionally substituted five- or six-membered ring containing at least one ring hetero atom selected from the group consisting of oxygen, sulfur and nitrogen,

Guanidine derivatives

Novel insecticidal pyrazolines of the formula ##STR1## wherein R.sup.1 and R.sup.2 represent hydrogen, C.sub.1-4 alkyl, or unsubstituted or halogen substituted phenyl,

Insecticidal pyrazolines

A cyano compound useful as an insecticide, of the formula (I) ##STR1## wherein the radicals are defined in the claims.

Insecticidally active cyano compounds

Insecticidal nitro-substituted heterocyclic compounds of the formula ##STR1## wherein R.sup.1 represents hydrogen, cyano or C.sub.1-4 alkyl,

Novel guanidine derivatives of the formula (I) ##STR1## wherein Z is 2-chloro-5-pyridyl, 2-chloro-5-thiazolyl, or 3-chloro-5-isoxazolyl,

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Tokyo, Japan

Yumi Hattori