Petrochina Company Limited

China Petrochemical Corporation

Institute of Chemical Metallurgy Academia Sinica

Sinopec Beijing Design Institute (bdi)

Yulong Li

Ning Zhang

Jingyuan Zhang

Qian Chen

Sihan Wang

Yongjun Zhang

Hongxia Chen

Guizhi Wang

Baojun Zhang

Qiye Yang

Deshun Zhang

Shukun Sun

Jianzhong Li

Yongcheng Sun

Huimin Yuan

Yunguang Han

Baolin Luo

Kuiyuan Sun

Mingli Gong

Yihou Hu

Jiyu Hu

Guoping Fang

Lihua Xing

Yingnan Ning

Dongting Kuang

The present invention relates to a catalyst composition for ethylene oligomerization and the use thereof. Such catalyst composition includes chromium compound, ligand containing P and N, activator and accelerator; wherein the chromium compound is selected from the group consisting of acetyl acetone chromium, THF-chromium chloride and Cr(2-ethylhecanoate); general formula of the ligand containing P and N is shown as: in which R, R, Rand Rare phenyl, benzyl, or naphthyl. Ris isopropyl, butyl, cyclopropyl, cyclopentyl, cyclohexyl or fluorenyl; the activatior is methyl aluminoxane, ethyl aluminoxane, propyl aluminoxane and/or butyl aluminoxane; the accelerator is selected from the group consisting of 1,1,2,2,-tetrachloroethane, 1,1,2,2-tetrabromoethane, 1,1,2,2-tetrafluoroethane, and compounds having a formula of XRX, in which Xand Xare F, Cl, Br, I or alkoxyl, Ris alkylene or arylene group; the molar ratio of chromium compound, ligand containing P and N, activator and accelerator is 1:0.5&#x2dc;10:50&#x2dc;3000:0.5&#x2dc;10. After mixing the four components mentioned previously under nitrogen atmosphere for 10 minutes, they are incorporated to the reactor, or these four components are incorporated directly into the reactor. Then ethylene is introduced for oligomerization. Such catalyst can be used in producing 1-octene through ethylene oligomerization. It is advantageous in high catalysing activity, high 1-octene selectivity, etc. The catalytic activity is more than 1.0&#xd7;10g product&#xb7;maCr&#xb7;h, the fraction of Clinear &#x3b1;-olefin is more than 70% by mass.

Catalyst composition for ethylene oligomerization and the use thereof

This invention provides a novel dry chemical process for removing by carbonylation the metals harmful to the catalyst activity from the catalyst for the residuum and/or heavy oil catalytic cracking, comprising: contacting the catalyst contaminated by the poisonous metals with an activation gas and a reduction gas in a reactor for activation and reduction; and then in a carbonylation reactor, contacting the catalyst treated by activating and reducing with CO gas to make the metals on the catalyst carbonylated to form gaseous metal carbonyls which are then transferred and separated from the solid catalyst, thereby the catalyst activity is restored. The process of this invention is simple in the technology, moderate in the operation conditions, and it will not cause secondary pollution to environment for there is no addition and discharge of any liquid.

Dry regeneration-demetalization technique for catalyst for residuum

Growing community of inventors

Beijing, China

Yulong Li