Taoka Chemical Company, Limited

Yukinori Nishino

Hiroaki Yamamoto

Chiaki Hata

Eizo Kajigaki

Yoshio Nagahama

Kizuku Wakatsuki

Provided is a 2-cyanoacrylate-purifying method for decoloring a 2-cyanoacrylate which has been colored, and preventing further coloring of the 2-cyanoacrylate thus decolored. The 2-cyanoacrylate-purifying method includes the steps of: (a) adding a specific polyhydric aromatic compound to the 2-cyanoacrylate which has been colored; and (b) storing, at a temperature in a range of 0&#xb0; C. to 40&#xb0; C. for 0.5 day or more, the resulting mixture obtained in the step (a), and then subjecting the mixture to reduced pressure distillation.

2-cyanoacrylate-purifying method

The present invention provides an ethyl-2-cyanoacrylate adhesive composition obtained as a result of significant improvement on conventional problems, that is, irritating odor and whitening of conventional ethyl-2-cyanoacrylate adhesive compositions. According to a method of the present invention for purifying an ethyl-2-cyanoacrylate adhesive composition, a sum total of an acrylonitrile content and an ethanol content is arranged to be in a range of 1 ppm to 150 ppm, by carrying out deaeration at the same time as injection of an inactive gas at a reduced pressure in a range of 100 Pa to 10000 Pa at a temperature in a range of 5&#xb0; C. to 50&#xb0; C. Thereby, the method of the present invention allows improving irritating odor and whitening.

Method for purifying ethyl-2-cyanoacrylate adhesive composition and ethyl-2-cyanoacrylate adhesive composition

An &#x3b1;-cyanoacrylate adhesive system, having an excellent fast setting property in the adhesion of hardly adhering materials and porous materials; having an excellent storage stability, even when a plastic material is used for at least a part of container for the adhesive composition, nozzle, cap and tube; using an &#x3b1;-cyanoacrylate adhesive composition comprising an &#x3b1;-cyanoacrylate and 0.05 to 5.0% by weight, based on said &#x3b1;-cyanoacrylate, of 12-crown-4-ether; and using a container for containing the adhesive composition, a nozzle and a cap, and optionally a tube for sending the adhesive composition to the nozzle, at least a part of said container, nozzle, cap and tube being made of a plastic material is provided.

&#x3b1;-cyanoacrylate adhesive systems

An .alpha.-cyanoacrylate adhesive composition having high thixotropy, excellent stability with age including difficulty of separation and excellent adhesiveness, for use of rubbers, plastics, metals or so, comprises (b) 10 through 20 parts by weight of polymers containing alkyl methacrylate having a weight average molecular weight of 100,000 through 300,000, (c) 2 through 20 parts by weight of ultrafine anhydrous silica, and (d) 0.001 through 20 parts by weight of quick curing additives represented by the formula (1), (b)-(d) being on the basis of (a) 100 parts by weight of .alpha.-cyanoacrylates: ##STR1## wherein X.sub.1 is a hydrogen atom or methyl group; X.sub.2 is a hydrogen atom, methyl group or cyano group; X.sub.3 is R.sub.2 or R.sub.2 CO in which R.sub.2 represents a hydrocarbon residue containing no anionically polymerizable group; and l, m and n are integers and (l+m).gtoreq.1 and n.gtoreq.1.

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Osaka, Japan

Yukinori Nishino