Kaneka Corporation

Yukihiro Shimamoto

Kazuhito Wada

Taizo Aoyama

Kouji Morita

Juichi Nishimura

Katsumi Yamaguchi

Keisuke Hatano

Haruki Koyama

Hideyuki Sakamoto

Fujio Ishimaru

Takahiro Furo

Hanako Hasebe

An acrylic resin film is provided that may include graft copolymer particles (A) with a multilayer structure and graft copolymer particles (B) with a multilayer structure, wherein the graft copolymer particles (A) may have an average particle size in the range of 20 to 150 nm, the graft copolymer particles (B) may have a larger average particle size than the graft copolymer particles (A). The graft copolymer particles (A) may include a cross-linked elastomer (A1) and a graft polymer layer (A2), the graft polymer layer (A2) being closer to a surface layer than the cross-linked elastomer (A1). Further, a constituent unit may be derived from an acrylate with an alkyl ester moiety having two or more carbon atoms constitutes 8% or less by mass of the graft polymer layer (A2), the graft copolymer particles (B) may contain a cross-linked elastomer (B1).

Acrylic resin film, laminated film, production method for laminated film, and molded article

An object of the present invention is to provide a novel monolayer and multilayer film that can be employed also for use in interior and exterior members of vehicles, and that have excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin film formed with (C) a fluororesin comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl(meth)acrylate polymer component; and a fluororesin-laminated acrylic resin film, wherein the fluororesin film layer is laminated on at least one face of a film layer comprising (A) an acrylic resin.

Fluororesin film and fluororesin-laminated acrylic resin film

Provided are a fluorine-containing (meth)acrylic (co)polymer that scarcely generates gas when subjected to molding process, and is capable of supplying a molded body excellent in external appearance and transparency; a fluorine-containing (meth)acrylic resin film thereof; and a fluororesin laminated resin film having the same properties. The (co)polymer is a fluorine-containing (meth)acrylic (co)polymer obtained by polymerizing a monomer component including 100 to 70% by weight of a fluoroalkyl(meth)acrylate monomer, and 0 to 30% by weight of a different monomer copolymerizable therewith by effect of a radical polymerization initiator having a solubility in water of 0.1% or less by weight at 25 C, and having 8 to 14 carbon atoms.

Fluorine-containing (meth) acrylic (co) polymer and molded body films thereof

Disclosed herein is an acrylic resin film having excellent heat resistance and mechanical strength, less fish-eyes, and high transparency. The acrylic resin film is obtained by molding a resin composition containing a glutarimide acrylic resin (G) and a (meth)acrylic resin (F) obtained by polymerization of a vinyl group-containing compound in the presence of alkyl acrylate-based cross-linked elastic particles having an average particle size of less than 80 nm.

Acrylic resin film

Acrylic matt thermoplastic resin films having excellent printability, flex whitening resistance, impact resistance and solvent resistance, and a process for the preparation thereof are provided. The films made of a thermoplastic resin composition comprising 100 parts by weight of an acrylic resin (A) and 0.5 to 20 parts by weight of a crosslinked acrylic polymer (B) as a matting agent are prepared by a process wherein the resin composition is kneaded and formed into a film, and the both surfaces of the film are simultaneously brought into contact with rolls between them, one roll being kept at a temperature of not less than the glass transition temperature Tg of the resin composition and the other roll being kept at a temperature of less than the Tg, whereby the film surface contacted with the roll having a temperature of Tg or higher is converted into a mirror surface and the film surface contacted with the roll having a temperature lower than Tg is converted into a matt surface.

Acrylic matt thermoplastic resin films and process for producing the same

A method for producing a vinylidene fluoride resin film having excellent transparency, weather resistance, chemical resistance, break resistance and formability is provided. The film is shaped by sandwiching a vinylidene fluoride resin in a molten state between rollers or metal belts so as to let them cool down, thus realizing polyvinylidene fluoride with a fine average spherocrystal diameter. Thus, the vinylidene fluoride resin film having the above-stated properties can be obtained.

Method for producing vinylidene fluoride resin transparent film

A vinylidene fluoride-based resin film including polyvinylidene fluoride whose average spherocrystal diameter is less than 0.1 &#x3bc;m that is a detection limit or lower by observation using a transmission electron microscope is provided, the average spherocrystal diameter being obtained by shaping a vinylidene fluoride-based resin in a molten state by sandwiching the resin between rollers or metal belts so as to let it cool down. Thereby, a vinylidene fluoride-based resin film and a vinylidene fluoride-based resin multilayered film having excellent transparency, weather resistance, chemical resistance, break resistance and formability are provided.

Growing community of inventors

Settsu, Japan

Yukihiro Shimamoto