Fuji Photo Film Company, Limited

Fujifilm Corporation

Yukihiro Katai

Tadahiro Tsujimoto

Hidekazu Yamazaki

Toshikazu Nakamura

Misao Takahashi

Seiji Kasahara

Toshinao Arai

Shigehisa Sugiyama

Tooru Ogura

Yasuhisa Shimoda

Masahiro Esaki

Takuro Nishimura

The present invention provides a nanofiber manufacturing method and a nanofiber manufacturing device. A solutionin which a polymer is dissolved in a solvent is supplied from a distal end of a nozzleto form a Taylor coneat a distal end opening. By applying a voltage between the solutionand a collectorusing a power supply portion, an electrospinning jetis sprayed from the Taylor coneto the collector. At the start or stop of electrospinning, a blocking memberis inserted into a spraying areaof the electrospinning jetsuch that an unstable electrospinning jet or unstable nanofibers are received. A product is not manufactured from an unstable electrospinning jet formed at the start or stop of electrospinning, and the manufacturing of a defective product is prevented.

Nanofiber manufacturing method and nanofiber manufacturing device

A fiber manufacturing method includes the following steps of: dissolving a polymer in a solvent to obtain a polymer solution; spraying the polymer solution into a liquid heated to a boiling point of the solvent or higher, and evaporating the solvent to precipitate a fibrous polymer in a sealed precipitation tank, the liquid being immiscible with the polymer and the solvent; conveying the precipitated fibrous polymer in a liquid from the precipitation tank; water-rinsing the fibrous polymer conveyed in the liquid in the conveying step in a sealed water-rinsing tank; conveying the water-rinsed fibrous polymer in a liquid from the water-rinsing tank; and cooling and condensing solvent gas that is generated in the spraying step and the water-rinsing step.

Fiber manufacturing method, non-woven fabric manufacturing method, and fiber manufacturing equipment

A solvent and TAC particles are continuously supplied to a disperser. When the shearing of the solvent and the particles are made in a shearing section, the particles are dispersed in the solvent. The dispersion is fed to a mixer in one minute. The shearing of the dispersion is made in the mixer, the particles are swollen in the solvent in one minute. Since the shearing and the continuous feed of the swelling solution is made, the aggregation does not occur. There are no undissolved aggregates in a dope, which is obtained from the swelling solution. A film produced from the dope has no defects of luminescent spot but excellent optical properties.

Method of producing dispersion

A camera for capturing a casting bead is provided at each side end of a discharge port in a width direction thereof. Plural speakers are provided at the vicinity of an opening of a decompression chamber. The camera continuously captures the casting bead, and outputs image data thereof to a control unit. The control unit includes a vibration detector and a suppressing vibration generator. The vibration detector detects vibration of the casting bead based on the plural image data. The suppressing vibration generator generates suppressing vibration signal representing the phase and amplitude of the suppressing vibration for suppressing the vibration generated in the thickness direction of the casting bead. The control unit controls the speakers based on the suppressing vibration signal to output sound wave. Thereby, the suppressing vibration is applied to the casting bead.

Solution casting method and apparatus

The solution film-forming method is provided in which the absolute filtration accuracy for a cellulose acylat solution can be improved and filtration throughput can be increased without reducing the pore size of a filtering material. A dope stock solution to be filtrated is first introduced into a body feed tank and a filter aid from a filter aid tank is added and dispersed. As the filter aid, an aid including SiO2 in 50% or more and a cellulose-based aid are mixed for use. The dope stock solution in which the filter aid is dispersed is introduced into a filter machine and subjected to filtration while forming a cake on the surface of the filtering material. After the filtration, a cleaning solvent is supplied in circulation from a cleaning solvent tank, and the cake is discharged as slurry. The filter aid is separated from the slurry by a separating device and burned in a burning device. Then, a regenerated filter aid is sent to the filter aid tank. After the cleaning, a precoat liquid in which the filter aid is dispersed is supplied from a precoat tank to the filter machine to form a precoat layer on the surface of the filtering material.

Solution film-forming method

TAC and additives are mixed in a mixture solvent of dichloromethane, methanol and n-butanol to obtain a dispersion solution. The dispersion solution is heated to become a low concentration dope whose concentration is 19.3 wt. %. The low concentration dope is fed with a pump, and supplied through a flash nozzle to a concentrating apparatus to performing flash evaporation of the solvent in the concentrating apparatus. Thus part of the solvent in the low concentration dope evaporates to obtain a condensed dope. The part of the solvent is condensed on a condensation surface to obtain a condensed solvent. The condensed solvent flows through a pipe out of the concentrating apparatus. The high concentration dope has a solid content of 22.3 wt. %, and drawn through a pump. As the solid content of the high concentration dope is high, a polymer film having the self-supporting property can be easily formed of the high concentration dope in a film production line.

Method of producing high concentration polymer solution

An low concentration dope is fed through a nozzle into a concentrating apparatus, and flash evaporation of the low concentration dope is performed at an end of the nozzle. The low concentration dope is concentrated thereby to an concentrating dope which is contained and heated in the concentrating apparatus. Thus part of solvents of the low concentration dope and the concentrating dope is evaporated to a solvent gas. The solvent gas is cooled and condensed in a condensing section of the concentrating apparatus, and thereafter drawn through a first exit from the concentrating apparatus. The concentrating dope is concentrated to a high concentration dope, which is drawn through a second exit from the concentrating apparatus.

Method for concentrating solution

An apparatus for the preparation of polymer solutions contains a stirring device, a cooling device connected to the stirring device and a warming device connected to the cooling device. Both the warming device and the cooling device are characterized by including a rotary screw. The stirring device functions to mix a polymer with a solvent to produce a swelled polymer in the solvent. The incorporation of a screw into the warming or cooling device allows the temperature of the solution to change while simultaneous mixing and shear is provided.

Apparatus containing cooling and warming devices for the preparation of a polymer solution

In the transparent film of optical application or the support for photographic material produced by a solution film forming method, the polymer resin film on which any coating unevenness does not occur even when a functional layer is coated on the film surface and the manufacturing method for the film are proposed. To be concrete, a polymer resin film produced by the solution film forming method characterized by that the pitch a [cm] of the periodic thickness unevenness of web longitudinal direction and a thickness unevenness factor d [%] satisfy formula (1) described below.&#x2212;0.910.6+1.01&#x2003;&#x2003;(1) The manufacturing method using said formula is also proposed.

Polymer resin film and its production

In the transparent film of optical application or the support for photographic material produced by a solution film forming method, the polymer resin film on which any coating unevenness does not occur even when a functional layer is coated on the film surface and the manufacturing method for the film are proposed. To be concrete, a polymer resin film produced by the solution film forming method characterized by that the pitch a [cm] of the periodic thickness unevenness of web longitudinal direction and a thickness unevenness factor d [%] satisfy formula (1) described below.0.46&#x2212;0.910.6&#x2003;&#x2003;(1) The manufacturing method using said formula is also proposed.

A novel apparatus for the preparation of a polymer solution includes a stirring device, an extruder connected to the stirring device, a cooling device connected to the extruder, and a warming device connected to the cooling device. The extruder is a fiber or membrane extruding die. Both the cooling device and warming device are vessels.

A cellulose acylate film formed from a solution of cellulose acylate contains a solvent of the solution at 0.1-0.6 wt. %, and acids at less than 500 ppm. The solvent is composed of at least one of esters and ketones, and further a recycled solvent recycled from the solution. In order to produce the cellulose acylate film, the solution is applied on a dope band moving in a direction, and dried to contain the solvent between 10-80 wt. % to the cellulose acylate. Thus a film-like material is formed from the solution, and peeled from the dope band. Thereafter the film-like material is further dried to form the cellulose acylate film containing the solvent at between 0.1 and 0.6 wt. %.

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Kanagawa, Japan

Yukihiro Katai